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Resistance to the Fumigant Phosphine and Its Management in Insect Pests of Stored Products: A Global Perspective.

Annual Review of Entomology, 2020
Development of resistance in major grain insect pest species to the key fumigant phosphine (hydrogen phosphide) across the globe has put the viability and sustainability of phosphine in jeopardy.
M. Nayak   +3 more
semanticscholar   +1 more source

Asymmetric Synthesis of P-Stereogenic Secondary Phosphine-Boranes by an Unsymmetric Bisphosphine Pincer-Nickel Complex.

Journal of the American Chemical Society, 2021
The first highly enantioselective catalytic synthesis of P-stereogenic secondary phosphine-boranes was realized by the asymmetric addition of primary phosphine to electron-deficient alkenes with a newly developed unsymmetric bisphosphine (PCP') pincer ...
Chuanyong Wang   +3 more
semanticscholar   +1 more source

Cobalt-Catalysed Asymmetric Addition and Alkylation of Secondary Phosphine Oxides for the Synthesis of P-Stereogenic Compounds.

Angewandte Chemie, 2021
The catalytic asymmetric synthesis of P-chiral phosphorus compounds is an important way to construct P-chiral ligands. Herein, we report a new strategy that adopts the pyridinyl moiety as the coordination group in the cobalt-catalysed asymmetric ...
Wei-Liang Duan   +9 more
semanticscholar   +1 more source

Palladium/Xiao-Phos-Catalyzed Kinetic Resolution of sec-Phosphine Oxides by P-Benzylation.

Angewandte Chemie, 2021
P-stereogenic tert- and sec-phosphines have wide applications in asymmetric catalysis, materials, and pharmaceutical chemistry, however, their practical synthesis still constitutes a significant challenge.
Junliang Zhang, Q. Dai, Lu Liu
semanticscholar   +1 more source

Enantioselective Palladium-Catalyzed Hydrophosphinylation of Allenes with Phosphine Oxides: Facile Access to Chiral Allylic Phosphine Oxides.

Angewandte Chemie, 2021
A Pd-catalyzed hydrophosphinylation of alkyl and aryl-oxyallenes with phosphine oxides has been developed for the efficient and rapid construction of a family of chiral allylic phosphine oxides with a diverse range of functional groups.
Zhiping Yang, Jun Wang
semanticscholar   +1 more source

Phosphine Oxides from a Medicinal Chemist's Perspective: Physicochemical and in vitro Parameters Relevant for Drug Discovery.

Journal of Medicinal Chemistry, 2020
Phosphine oxides and related phosphorus-containing functional groups such as phosphonates and phosphinates are established structural motifs that are, still, underrepresented in today's drug discovery projects, and only few examples can be found amongst ...
Peter Finkbeiner, J. P. Hehn, C. Gnamm
semanticscholar   +1 more source

Analysis of the characteristics of phosphine production by anaerobic digestion based on microbial community dynamics, metabolic pathways, and isolation of the phosphate-reducing strain.

Chemosphere, 2021
Although phosphine is ubiquitously present in anaerobic environments, little is known regarding the microbial community dynamics and metabolic pathways associated with phosphine formation in an anaerobic digestion system.
Yimin Fan   +5 more
semanticscholar   +1 more source

Intramolecular Phosphine−Phosphine Donor−Acceptor Complexes

Inorganic Chemistry, 2009
The reaction of 5-diphenoxyphosphanyl-6-diisopropylphosphinoacenaphthene 12 with chlorotrimethylsilane unexpectedly gave a phosphonium-phosphine compound 13, containing the structural motif of four phosphorus atoms connected in a chain. To explain the mechanism of this complex transformation, a proposed intermediate 5-dichlorophosphino-6 ...
Piotr, Wawrzyniak   +3 more
openaire   +2 more sources

Phosphine-Based Covalent Organic Framework for the Controlled Synthesis of Broad-Scope Ultrafine Nanoparticles.

Small, 2020
In this work, a phosphine-based covalent organic framework (Phos-COF-1) is successfully synthesized and employed as a template for the confined growth of broad-scope nanoparticles (NPs).
Rao Tao   +11 more
semanticscholar   +1 more source

ChemInform Abstract: Phosphine—Phosphine Oxides, Phosphine—Carboxylic Acids and Phosphines Bearing Olefinic Groups

ChemInform, 2009
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Benjamin Schaeffner, Armin Boerner
openaire   +1 more source

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