Results 31 to 40 of about 131,045 (252)

A pendant proton shuttle on [Fe4N(CO)12]- alters product selectivity in formate vs. H2 production via the hydride [H-Fe4N(CO)12]. [PDF]

, 2016
Proton relays are known to increase reaction rates for H2 evolution and lower overpotentials in electrocatalytic reactions. In this report we describe two electrocatalysts, [Fe4N(CO)11(PPh3)]- (1-) which has no proton relay, and hydroxyl-containing [Fe4N(
Banales, Carolina L, Berben, Louise A, Fettinger, James C, Kagan, Michael, Loewen, Natalia D, Myers, Thomas W, Thompson, Emily J   +6 more
core   +2 more sources

Electrochemically Driven Dissipative Growth of Affinity Hydrogels for Bioresponsive Interfaces

Advanced Functional Materials, EarlyView.
Voltage pulses drive the growth and reinforcement of hydrogel films under dissipative conditions. This biocompatible strategy enables efficient integration of affinity ligands into the hydrogel matrix, enhancing the selective capture of growth factors and allowing precise temporal control over their release, making them well‐suited as adaptive ...
Roberto Baretta, Marco Frasconi
wiley   +1 more source

Encoding Magnetic Anisotropies in Digital Light Processing 3D Printing

Advanced Functional Materials, EarlyView.
A hybrid magnetic device—combining a coaxial coil within a nested Halbach array—is presented, integrated into a DLP 3D printer to enable spatially resolved magnetic field control. This system enables complex, multimodal responses by programming liquid crystal elastomer resins for magnetic and thermal actuation, and by inducing electrically conductive ...
Eléonore Aïdonidis, Andrea Cosola, Pierre Bourdon, Hichem Dammak, Marco Sangermano, Frédéric Demoly, Marco Faustini, Amélie Pérot, Didier Lairez, Rakine Mouhoubi, Sébastien Blanquer, Giancarlo Rizza   +11 more
wiley   +1 more source

A new xantphos-type ligand and its gold(I) complexes: Synthesis, structure, luminescence [PDF]

, 2013
A novel xantphos analog diphosphine ligand, 9,9-dimethyl-4,5-bis(diphenylphosphinomethyl)-9H-xanthene (X(CP)2), with methylene groups inserted between the xanthene skeleton and the two diphenylphosphine units, has been synthesized. A two-coordinate and a
Baranyai, Péter, Besenyei, Gábor, Bitter, István, Faigl, Ferenc, Grün, Alajos, Kubinyi, Miklós, Kunsági-Máté, Éva, Párkányi, László, Szalontai, Gábor   +8 more
core   +1 more source

Controlling 3D Contractility via Engineered Fibrous Hydrogel Composites

Advanced Functional Materials, EarlyView.
A tunable composite contractile assembly (CCA) is developed that can permit or resist contraction without changing cell‐adhesion and density, unlike collagen whose inherent coupling of these ECM cues limits its use as a platform in contractility studies.
Karen L. Xu, Yuqi Zhang, Alysse DeFoe, Georgios Kotsaris, Brendan Stoeckl, Matthew D. Davidson, Jason A. Burdick, Robert L. Mauck   +7 more
wiley   +1 more source

Dihydrogen and Acetylene Activation by a Gold(I)/Platinum(0) Transition Metal Only Frustrated Lewis Pair [PDF]

, 2017
The first example of a Frustrated Lewis Pair (FLP) solely constructed around transition metal centers is described in this work. We have focused on the established capacity of Au(I) and Pt(0) complexes to act as Lewis acidic and basic frag-ments ...
Campos, Jesús
core   +4 more sources

Novel Functional Materials via 3D Printing by Vat Photopolymerization

Advanced Functional Materials, EarlyView.
This Perspective systematically analyzes strategies for incorporating functionalities into 3D‐printed materials via Vat Photopolymerization (VP). It explores the spectrum of achievable functionalities in recently reported novel materials—such as conductive, energy‐storing, biodegradable, stimuli‐responsive, self‐healing, shape‐memory, biomaterials, and
Sergey S. Nechausov, Patrick Fesser, Boris A. Bulgakov, Ulrich S. Schubert   +3 more
wiley   +1 more source

Synthesis of neutral nickel catalysts for ethylene polymerization – the influence of ligand size on catalyst stability [PDF]

, 2003
A facile synthesis of nickel salicylaldimine complexes with labile dissociating ligands is described. In addition to producing highly active ethylene polymerization catalysts, important insights into the effect of ligand size on catalyst stability and ...
Connor, Eric F., Grubbs, Robert H., Henderson, Jason I., Waltman, Andrew W., Younkin, Todd R.   +4 more
core   +1 more source

Spectrophotometric studies of the photolysis of diazido-bis(phosphine)-metal(II) complexes [PDF]

, 1993
The photolysis of mixed ligand complexes of the type MLn(N3)2 (M=Ni, Pd, Pt; L = phosphane and diphosphane ligands, respectively; n = 1, 2) was monitored by electronic spectroscopy in absorption, emission and excitation.
Hennig, H., Knoll, H., Ritter, K., Vogler, Arnd   +3 more
core   +1 more source

Dual‐Site Ru Single‐Atoms and RuP Nanoclusters on N, P, and B Co‐Doped Porous Carbon for Efficient Alkaline HER and AEM Water Electrolysis

Advanced Functional Materials, EarlyView.
Ru single atoms and RuP nanoclusters are co‐anchored in N, P, and B co‐doped porous carbon nanospheres via in situ carbonization/phosphidation of a boronate polymer precursor. RuP activates water, while nearby Ru single atoms accelerate H2 formation through H* transfer. The catalyst delivers low overpotential and high durability in alkaline HER and AEM
Xiaohong Wang, Juguo Dai, Dongxu Li, Jianghua Wu, Hucheng Fu, Yiting Xu, Xueqiang Qi, Qian Xue, Yanbin Shen, Xiaoqing Pan, Conghui Yuan, Shuifen Xie, Andreu Cabot, Lizong Dai   +13 more
wiley   +1 more source