Results 271 to 280 of about 38,475 (330)

Advances in Copper and Nickel C─N and C─O Cross‐Couplings of (Hetero)Aryl Chlorides Enabled by Ancillary Ligand Development

open access: yesChemistry – A European Journal, EarlyView.
Important recent advances in ancillary ligand design that enable superlative copper or nickel catalyst systems for C─N or C─O cross‐couplings of inexpensive and abundant (hetero)aryl chloride electrophiles under operationally simple thermal conditions are discussed. Abstract The evolution of palladium‐catalyzed C─N and C─O cross‐coupling chemistry into
Kathleen M. Morrison, Mark Stradiotto
wiley   +1 more source

Functionalized in Triplicate: A Ring‐By‐Ring Approach to Tailored Prodiginine Derivatives for Site‐Specific Conjugation Through Click Chemistry

open access: yesChemistry – A European Journal, EarlyView.
Prodigiosin is a potent cytotoxic alkaloid but lacks target selectivity. We advance functionalization of all three pyrrole rings of prodigiosin to enable site‐specific conjugation via click chemistry. The presented azide‐ and maleimide‐functionalized prodiginines are suitable for generating covalent prodiginine conjugates and attaching auspicious ...
T. Moritz Weber, Jörg Pietruszka
wiley   +1 more source

Recent advances in the electrochemical synthesis of organophosphorus compounds. [PDF]

open access: yesBeilstein J Org Chem
Kaboudin B   +3 more
europepmc   +1 more source

Few Steps, Big Impact: Recent Advances in the Streamlined Synthesis of Multiply Chiral Heterohelicenes with Tunable Optoelectronic Properties

open access: yesChemistry–Methods, EarlyView.
Heterohelicenes with multiple chiral axes have the potential to drive next‐generation technologies due to their unique structural and optoelectronic features. This review highlights innovative short‐step synthetic strategies for double and triple heterohelicenes, emphasizing their ease of preparation and valuable (chir)optical features, along with high
Mohamed S. H. Salem, Shinobu Takizawa
wiley   +1 more source

High-Efficiency Light Emitters: 10-(Diphenylphosphoryl)-anthracenes from One-Pot Synthesis Including C-O-P to C-P(═O) Rearrangement. [PDF]

open access: yesJ Org Chem
Vivek V   +7 more
europepmc   +1 more source

Bombyx Mori Silk Fibroin as a Sustainable Organocatalyst for Diastereoselective Michael Additions

open access: yesChemSusChem, EarlyView.
Silk fibroin, natural biopolymer, has been successfully used as green catalyst for Michael addition reactions under mild conditions. Its pseudoenzymatic pocket enables enzyme‐like catalytic behavior, driving stereoselectivity, and highlighting a sustainable, nature‐inspired catalytic approach.
Carola Ricciardelli   +8 more
wiley   +1 more source

Modular, Tricomponent, and Concurrent One‐Pot Synthesis of Libraries of γ‐Keto Sulfones and γ‐Keto Phosphine Oxides using Brønsted Acidic Eutectic Mixtures

open access: yesChemSusChem, EarlyView.
This study presents a sustainable, metal‐free, one‐pot synthesis of γ‐keto sulfones and phosphine oxides using a ChCl/p‐TSA·H2O eutectic mixture. The method enables regioselective CC and CX bond formation under mild conditions, aligning with Green Chemistry Principles.
Marina Ramos‐Martín   +2 more
wiley   +1 more source

Phosphorus-Derived Isatin Hydrazones: Synthesis, Structure, Thromboelastography, Antiplatelet, and Anticoagulation Activity Evaluation. [PDF]

open access: yesInt J Mol Sci
Samorodov AV   +10 more
europepmc   +1 more source

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