Recyclable Ligand‐free Cobalt Catalyst for Alkoxycarbonylation of Chloroacetates
Direct carbonylation of the C(sp3)‐Cl bond remains a challenging transformation in the chemical industry. The usual use of precious metals, the high cost of ligands and the lack of recyclability of catalysts make their industrial application on a large scale impossible.
Wenyu Wang+6 more
wiley +1 more source
Asymmetric copper-catalyzed hydrophosphinylation of ethynylazaarenes to access <i>P</i>-chiral 2-azaaryl-ethylphosphine oxides. [PDF]
Zhang J+7 more
europepmc +1 more source
Effects of Concurrent Sulfur and Phosphorus Incorporation in Nickel Cyclam‐Based Complexes
The concurrent incorporation of phosphorus and sulfur into cyclam is investigated by the synthesis of the P, S, N‐containing 14‐membered macrocycles and their corresponding nickel complexes, which exist in both square‐planar and octahedral geometries.
Tatiana Guseva+6 more
wiley +1 more source
Functionalized Terthiophene as an Ambipolar Redox System: Structure, Spectroscopy, and Switchable Proton-Coupled Electron Transfer. [PDF]
Käch D+3 more
europepmc +1 more source
Microwave-Assisted P-C Coupling of the Less Reactive Chlorobenzene and >P(O)H Reagents in the Absence of the Usual Mono- and Bidental P-Ligands. [PDF]
Huszár B, Mucsi Z, Keglevich G.
europepmc +1 more source
The Synthesis, Crystal Structure, Modification, and Cytotoxic Activity of α-Hydroxy-Alkylphosphonates. [PDF]
Szalai Z+7 more
europepmc +1 more source
Isolable Three-Coordinate Base-Stabilized Alumylene: A Precursor of Persistent Acceptor-Free Monomeric Aluminum Oxide. [PDF]
Baeza JML+8 more
europepmc +1 more source
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Microemulsions with Alkyldimethyl Phosphine Oxides and Alkyldiethyl Phosphine Oxides
Langmuir, 2008Alkyldimethyl phosphine oxides (C n DMPO) as well as alkyldiethyl phosphine oxides (C n DEPO) with chain lengths of n = 10 (decyl), 12 (dodecyl), and 14 (tetradecyl) were synthesized and purified to study how the formation of microemulsions depends on the size of the headgroup and on the length of the alkyl chain.
Reinhard Strey+2 more
openaire +3 more sources
Reduction of phosphine oxides to phosphines
Tetrahedron Letters, 2019Abstract The digest is devoted to the most widespread reducing agents which are used for the reduction of tertiary and secondary phosphine oxides, phospholene oxides, phospholane oxides, phosphonates, phosphinates, α- and β-hydroxy and thiomethyl phosphine oxides, α-aminophosphine oxides. Stereoselectivity of reactions is described.
Ekaterina A. Kuchuk+3 more
openaire +2 more sources