Room-Temperature Alternative to the Arbuzov Reaction: The Reductive Deoxygenation of Acyl Phosphonates [PDF]
, 2010 The reductive deoxygenation of acyl phosphonates using a Wolff−Kishner-like sequence is described. This transformation allows direct access to alkyl phosphonates from acyl phosphonates at room temperature. The method can be combined with acyl phosphonate
Dougherty, Dennis A. +1 more
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Aminobromination of Unsaturated Phosphonates. [PDF]
ChemInform, 2003 AbstractFor Abstract see ChemInform Abstract in Full Text.
Xin, Qi +6 more
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Synthesis of 5-substituted 2'-deoxyuridine-5'-phosphonate analogues and evaluation of their antiviral activity [PDF]
, 2012 A small series of 5-(hetero)aryl-modified nucleoside phosphonates was synthesized via an 8-step procedure including a Wittig reaction and Suzuki-Miyaura coupling.
Balzarini, Jan +4 more
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Phosphonate–Phosphinate Rearrangement
The Journal of Organic Chemistry, 2015 LiTMP metalated dimethyl N-Boc-phosphoramidates derived from 1-phenylethylamine and 1,2,3,4-tetrahydronaphthalen-1-ylamine highly selectively at the CH3O group to generate short-lived oxymethyllithiums. These isomerized to diastereomeric hydroxymethylphosphonamidates (phosphate–phosphonate rearrangement).
Qian, Renzhe +2 more
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Platonic Relationships in Metal Phosphonate Chemistry: Ionic Metal Phosphonates [PDF]
Crystals, 2019 Phosphonate ligands demonstrate strong affinity for metal ions. However, there are several cases where the phosphonate is found non-coordinated to the metal ion. Such compounds could be characterized as salts, since the interactions involved are ionic and hydrogen bonding.
Konstantinos Xanthopoulos +7 more
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Journal of Engineering Studies and Research, 2020 Hydrogen phosphonate anions and monocyclohexylammonium cations interacting through hydrogen bonds conduct to the formation of a salt namely monocyclohexylammonium hydrogen phosphonate. In this structure, hydrogen phosphonate anions are linked by pairs through O—H···O hydrogen bonds leading to anionic dimers.
MODOU SARR +4 more
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First Supramolecular Sensors for Phosphonate Anions [PDF]
, 2013 Fluorescent tripodal anion sensors with a 1,3,5-triethylbenzene core display a turn-on fluorescence response to phosphonate and phosphate anions and may be used as optical sensors.
Anzenbacher, Pavel +6 more
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Probing Coherent Vibrations of Organic Phosphonate Radical Cations with Femtosecond Time-Resolved Mass Spectrometry [PDF]
, 2019 Organic phosphates and phosphonates are present in a number of cellular components that can be damaged by exposure to ionizing radiation. This work reports femtosecond time-resolved mass spectrometry (FTRMS) studies of three organic phosphonate radical ...
Ampadu Boateng, Derrick +2 more
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PPH dendrimers grafted on silica nanoparticles: surface chemistry, characterization, silver colloids hosting and antibacterial activity [PDF]
, 2013 Polyphosphorhydrazone (PPH) dendrimers have been grafted on silica nanoparticles, and the surface functions of the dendrimers have been derivatized to phosphonates with lateral poly(ethyleneglycol) (PEG) chains.
Caminade, Anne-Marie +6 more
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Nanocomposites and methods for synthesis and use thereof [PDF]
, 2009 Nanocomposite compositions and methods of synthesis of the compositions are described. In particular, liquid crystal-functionalized nanoparticles, liquid crystal-templated nanoparticles, nanocomposite compositions including the nanoparticles, and ...
Furman, Benjamin R. +3 more
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