Comprehensive perspectives of metal and metal-free C-H activation approaches in pyrimidines and related heteroarenes: scope, mechanistic insights, and synthetic utility. [PDF]
RSC AdvMirfarah A, Hatami S, Shiri A.
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Recent developments in antimicrobial small molecule quaternary phosphonium compounds (QPCs) - synthesis and biological insights. [PDF]
RSC Med ChemMcDonough D +3 more
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Coupling of unactivated alkyl electrophiles using frustrated ion pairs. [PDF]
NatureRoediger S +3 more
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Continuous Flow Techniques in the Total Synthesis of Jaspine B: Part II. [PDF]
J Org ChemGurský M +6 more
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Novel phosphonium and ammonium ionic liquids for green applications
, 2014 Scott Alan Grimes
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Allenic phosphonium borate zwitterions via a phosphonium allenylidene intermediate
Chemical Communications, 2021An unexpected alkynyl phosphane rearrangement with Lewis acids yield a phosphonium borato-allene zwitterion via a transient tricoordinate phosphorus electrophile.
Lucas C. Torres +2 more
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Charge Distribution of Phosphonium Ionic Liquids: Phosphonium versus Phosphate
Russian Journal of Physical Chemistry A, 2020X-ray photoelectron spectroscopy is used to study six trihexyltetradecyl phosphonium ionic liquids. The charge distribution in both the phosphonium cation and the phosphate anion is discussed in detail. We can conclude that the P 2p binding energy for the cationic phosphorus centre is lower than that of the anion-based phosphorus centre. The electronic
null Yan He, null Shuang Men
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Highly-metallized phosphonium polyelectrolytes
Chem. Commun., 2014The synthesis, characterization, and pyrolysis of a novel class of highly-metallized, redox-active polyelectrolytes that employ phosphorus as a scaffold for the installation of transition metals is described.
Amir, Rabiee Kenaree +3 more
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Polymer Zwitterions with Phosphonium Cations
Journal of the American Chemical Society, 2021Polymer zwitterions are of interest for numerous applications, many of which stem from their antifouling properties when used as hydrophilic coatings. However, the chemical compositions of polymer zwitterions remain limited, with synthetic variants most typically comprising ammonium cations.
Marcel U. Brown +2 more
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