Results 51 to 60 of about 35,646 (266)

Hand-holding and releasing between the anion and cation to change their macroscopic behavior in water

open access: yesGreen Energy & Environment, 2019
Despite the similarity of ionic liquid and zwitterion, their some properties such as conductivity and hydrophobicity are different. Here we developed a novel phosphonium salt having a dynamic covalent bond between anion and cation, enabling reversible ...
Kosuke Kuroda   +2 more
doaj   +1 more source

Dual‐Functional Polyphosphoesters for Gene Delivery: Synergistic Effects of Guanidinium and Hydrophobic Side Chains in Degradable Polymers

open access: yesAdvanced Healthcare Materials, EarlyView.
This study presents guanidinium‐ and indole‐functionalized polyphosphoesters as degradable, non‐viral gene delivery vectors. Through precise tuning of charge density and hydrophobicity, these polymers form stable polyplexes with low toxicity. Remarkably, minor structural changes yield up to 200‐fold differences in transfection efficiency, highlighting ...
Markus Kötzsche   +8 more
wiley   +1 more source

Diphenylphosphinoyl chloride as a chlorinating agent - The selective double activation of 1,2-diols [PDF]

open access: yes, 2006
© The Royal Society of Chemistry 2006Treatment of 1,2-diols with diphenylphosphinoyl chloride in pyridine produces beta-chloroethyl phosphinates which react with complete control of stereochemistry to give epoxides and azido-alcohols, useful ...
Asger B. Petersen   +25 more
core   +2 more sources

Convergent synthesis of phosphorodiamidate morpholino oligonucleotides (PMOs) by the H-phosphonate approach

open access: yesScientific Reports, 2023
Phosphorodiamidate morpholino oligonucleotides (PMOs) are a promising type of antisense oligonucleotides, but their challenging synthesis makes them difficult to access.
Taiki Tsurusaki   +5 more
doaj   +1 more source

A Solid State Zwitterionic Plastic Crystal With High Static Dielectric Constant

open access: yesAdvanced Materials, EarlyView.
Developing solid high dielectric constant materials has been a research focus in the energy storage field. In this research, we discovered a zwitterion with a plastic crystal phase. Due to the short‐range degree of freedom of the dipole moment for this zwitterion, a relatively high static dielectric constant has been achieved in its solid state ...
Zitan Huang   +7 more
wiley   +1 more source

Beyond Traditional RAFT Polymerization: Emerging Strategies and Future Perspectives; A Third Update

open access: yesAdvanced Science, EarlyView.
This review explores recent advances in the past five years for non‐traditional RAFT polymerization, focusing on new activation strategies, sustainable depolymerization, and integration with automated and AI‐driven synthesis. Together, these innovations advance polymer chemistry and reveal how the pieces of the non‐traditional RAFT puzzle are steadily ...
Vianna F. Jafari   +10 more
wiley   +1 more source

Phosphonium lipocations as antiparasitic agents [PDF]

open access: yesBioorganic & Medicinal Chemistry Letters, 2012
Phosphonium lipocations were synthesized and evaluated for inhibition of the development of Plasmodium falciparum and Trypanosoma cruzi, etiological agents of malaria and Chagas disease, respectively. Optimal phthalimides and 1,4-naphthoquinone-based lipocations were active in vitro at mid-high nM concentrations against P.
Timothy E, Long   +5 more
openaire   +2 more sources

Synthesis and Characterization of Fluorinated Phosphonium Ionic Liquids to Use as New Engineering Solvents

open access: yesChemEngineering, 2022
In this work, a set of novel fluorinated ionic liquids (FILs), based on different tetra-alkyl-phosphonium cations with perfluorobutanesulfonate and perfluoropentanoate anions, were synthesized and characterized in order to check their suitability to ...
María C. Naranjo   +5 more
doaj   +1 more source

Phosphine-porphyrin conjugates : a thesis presented in partial fulfilment of the requirements for the degree of Masterate of Science in Chemistry at Massey University, New Zealand [PDF]

open access: yes, 2000
The research carried out in this thesis comprises an investigation into the synthesis and characterisation of a variety of complexed phosphine-aldehydes, complexed phosphinoporphyrins, and phosphinoferrocene conjugates.
Lun, David James
core  

Poly(ionic liquid)s: platform for CO2 capture and catalysis

open access: yes, 2019
Capture and conversion of CO2 are of great importance for environment-friendly and sustainable development of human society. Poly(ionic liquid)s (PILs) combine some unique properties of ILs with that of polymers and are versatile materials for CO2 ...
Weber, Jens   +2 more
core   +1 more source

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