Results 101 to 110 of about 70,821 (371)

Multi‐Level Confinement Single‐Molecule Charge Transfer Activated PRET for Near‐Infrared Targeted Cell Imaging

open access: yesAdvanced Science, EarlyView.
The cascade supramolecular assembly of charge‐transfer arrays not only triggered a topological transformation from nanofiber to nanorod and vesicles, but also promoted single‐molecule phosphorescent resonance energy transfer, expanding phosphorescence emission at 500 nm to near‐infrared delayed fluorescence emission at 650 nm with a lifetime of 11.20 ...
Zhuo Lei   +5 more
wiley   +1 more source

Yb2‐Tb Upconversion in a Hetero‐Trimetallic Molecular Lanthanide Complex

open access: yesAngewandte Chemie, EarlyView.
Lanthanides are at the forefront of photon upconversion in molecular systems; however, the chemical nature of the lanthanides makes site‐specific coordination chemistry difficult to achieve. Here, we employ kinetically stabile building blocks to achieve hetero‐trimetallic 4f complexes with complete site‐specific chemical control.
Nicolaj Kofod   +8 more
wiley   +2 more sources

Record‐High Performance Hyperfluorescent OLEDs Achieved via Electronic Structure Control of Chlorine‐Diversified MR‐TADF Emitters

open access: yesAdvanced Science, EarlyView.
A late‐stage diversification strategy for the benchmark MR‐TADF emitter ω‐DABNA enables precise electronic structure control via chlorine‐activated functionalization. The resulting derivatives achieve tunable emission from 523 to 533 nm with record‐high EQE1000 up to 34.0% and excellent color purity (CIEy = 0.70–0.73), establishing a versatile platform
Taehwan Lee   +7 more
wiley   +1 more source

From Microscale to Nanoscale Shadow Electrochemiluminescence Microscopy

open access: yesAngewandte Chemie, EarlyView.
In this research we report on the label‐free shadow electrochemiluminescence (shadow ECL) microscopy of microscale and nanoscale objects. By systematically investigating various influencing factors—including optical configuration, electrode activity, frame averaging, exposure time, and particle arrangement—we further confirm the nano‐imaging potential ...
Xiaodan Gou   +5 more
wiley   +2 more sources

Urea‐Formaldehyde Resin Confined Silicon Nanodots Composites: High‐Performance and Ultralong Persistent Luminescence for Dynamic AI Information Encryption

open access: yesAdvanced Science, EarlyView.
Schematic illustration of SiNDs composite materials synthesis and its internal photophysical process mechanism. And an AI‐assisted dynamic information encryption process. ABSTRACT Persistent luminescence materials typically encounter an intrinsic trade‐off between high phosphorescence quantum yield (PhQY) and ultralong phosphorescence lifetime.
Yulu Liu   +9 more
wiley   +1 more source

Aminal‐linked Covalent Organic Frameworks for Light Energy Upconversion

open access: yesAngewandte Chemie, EarlyView.
Aminal‐linked covalent organic frameworks incorporating anthracene units are introduced as solid‐state platforms for triplet–triplet annihilation upconversion. The crystalline materials retain chromophore electronic properties and exhibit fluorescence quantum yields of up to 40%.
Mateusz Brzeziński   +7 more
wiley   +2 more sources

Photo‐Responsive Room‐Temperature Phosphorescent Films Exhibiting Photochromism and Time‐Dependent Phosphorescent Colors for Multilevel Anti‐Counterfeiting

open access: yesAdvanced Science, EarlyView.
A series of photo‐responsive polymers are prepared by a facile one‐pot in situ synthesis strategy, where RTP modules and photochromic units are systematically integrated into one polymer system. The triplet‐singlet Förster resonance energy transfer (TS‐FRET) between the donor and acceptor enables the material to exhibit time‐dependent phosphorescence ...
Ziyi Bai   +5 more
wiley   +1 more source

Conformation‐Controlled Double Phosphorescence Components From A Single Organic Molecule: Time‐Dependent and Excitation‐Dependent Wide‐Range Afterglow Color Change

open access: yesAdvanced Functional Materials
Double phosphorescence components from a single organic molecule is rarely reported before because most organic molecules must follow Kasha's rule and merely emit phosphorescence from T1 state.
Jingjuan Bai   +9 more
semanticscholar   +1 more source

High‐Efficiency TADF Dendritic Emitters Enabled by Synchronously Inhibiting Degenerated Triplet Excited States and Structural Relaxation Toward Solution‐Processed OLEDs with EQE Over 33%

open access: yesAdvanced Science, EarlyView.
Asymmetrical thermally activated delated fluorescence dendritic emitters are delicately constructed through symmetry breaking strategy, and near‐unity photoluminescence efficiency and excellent reverse intersystem crossing process are achieved via breaking the degeneracy of vibrational levels and boosting the spin flip of triplet excitons.
Xiaoxiang Yu   +9 more
wiley   +1 more source

Au42(PET)32 Nanocluster Sensitizer Unlocks the Annihilator Potential of Rubrene, Enabling High‐Performance NIR‐to‐Visible Photon Upconversion

open access: yesAngewandte Chemie, EarlyView.
A needle‐shaped gold nanocluster, Au42(PET)32, serves as a powerful triplet sensitizer, enabling rubrene to fully express its intrinsic annihilator capability (spin statistical factor f = 0.58). This sensitizer–annihilator pair achieves record‐high upconversion internal quantum yields of 21.4% (808 nm excitation) and 15.0% (936 nm excitation ...
Masaaki Mitsui   +2 more
wiley   +2 more sources

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