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Dissipative Regenerative Chemiluminescence in Water: A Perylene‐Based Out‐of‐Equilibrium Light‐Emitting System

open access: yesAngewandte Chemie, EarlyView.
Driven by sodium dithionite and hydrogen peroxide under mild aqueous conditions, a water‐soluble perylene bisimide undergoes reversible electron‐transfer cycles that generate its emissive excited state without dye decomposition. We define this out‐of‐equilibrium system as chemically fueled regenerative chemiluminescence (CFRCL), opening new avenues for
Luca Morgan   +5 more
wiley   +1 more source

Tunable Oxygen Connectivity in Carbaporphyrinoid Polymers on Metal Surfaces

open access: yesAngewandte Chemie, EarlyView.
Hydroxyl‐functionalized dicarbaporphyrinoid polymers synthesized on Au(111) enable tunable oxygen‐mediated connectivity under UHV conditions. Thermal activation yields one‐dimensional hydroxyl‐terminated polymers that can selectively evolve into either covalently‐linked dibenzo‐p‐dioxane architectures through intermolecular C–O–C coupling or two‐fold ...
Alberto Martínez‐Bajo   +14 more
wiley   +1 more source

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