Results 131 to 140 of about 88,628 (298)

Surface‐modified Ag@Ru‐P25 for photocatalytic CO2 conversion with high selectivity over CH4 formation at the solid–gas interface

Carbon Energy
Systematic optimization of the photocatalyst and investigation of the role of each component is important to maximizing catalytic activity and comprehending the photocatalytic conversion of CO2 reduction to solar fuels.
Chaitanya B. Hiragond, Sohag Biswas, Niket S. Powar, Junho Lee, Eunhee Gong, Hwapyong Kim, Hong Soo Kim, Jin‐Woo Jung, Chang‐Hee Cho, Bryan M. Wong, Su‐Il In   +10 more
doaj   +1 more source

Universally Accurate or Specifically Inadequate? Stress‐Testing General Purpose Machine Learning Interatomic Potentials

Advanced Intelligent Discovery, EarlyView.
We investigate MACE‐MP‐0 and M3GNet, two general‐purpose machine learning potentials, in materials discovery and find that both generally yield reliable predictions. At the same time, both potentials show a bias towards overstabilizing high energy metastable states. We deduce a metric to quantify when these potentials are safe to use.
Konstantin S. Jakob, Karsten Reuter, Johannes T. Margraf   +2 more
wiley   +1 more source

Synergistic Lewis Acid Photocatalysis Over Cluster‐Defect‐Engineered UiO‐66 for Efficient Liquid Biomass Upgrading

Angewandte Chemie, EarlyView.
A cluster‐defect engineering strategy is presented for the rational design of Zn‐incorporated UiO‐66 photocatalysts. Selective acid etching mediates hierarchical porosity and abundant Lewis acid sites, tailoring the electronic structure and enhancing light harvesting.
Hao Wang, Li‐Long Zhang, Haimei Xu, Baohua Jia, Liqun Ye, Tianyi Ma, Heng Zhang   +6 more
wiley   +2 more sources

Photocatalytic degradation of an organophosphorus compound by porous Au- and WO3- modified TiO2 [PDF]

, 2016
Organophosphorus (OP) compounds are highly toxic substances that are often used as chemical warfare agents and pesticides. OP pesticides are the most widely used class of pesticide in the world, and due to their ubiquity, the contamination of ...
Parker, David M.
core   +1 more source

Data‐Guided Photocatalysis: Supervised Machine Learning in Water Splitting and CO2 Conversion

Advanced Intelligent Discovery, EarlyView.
This review highlights recent advances in supervised machine learning (ML) for photocatalysis, emphasizing methods to optimize photocatalyst properties and design materials for solar‐driven water splitting and CO2 reduction. Key applications, challenges, and future directions are discussed, offering a practical framework for integrating ML into the ...
Paul Rossener Regonia, Christian Mark Pelicano   +1 more
wiley   +1 more source

Controlling Near‐Infrared Fluorescence‐to‐Phosphorescence Ratios and Triplet Lifetimes in Rhodium(I) Dimers via Primary and Secondary Coordination Sphere Effects

Angewandte Chemie, EarlyView.
RhI dimers with bridging aryl isocyanide and di‐phosphine ligands show NIR‐I or NIR‐II fluorescence/phosphorescence, depending on the ligands and conformational rigidity at the Rh2 core. Rh‐Rh interactions can be tuned by peripheral modification of the aryl isocyanide ligand, resulting in a rigid Rh2 core and improved photophysical properties ...
Vanitha R. Naina, Giacomo Morselli, Alessandro Prescimone, Daniel Häussinger, Oliver S. Wenger   +4 more
wiley   +2 more sources

Thermometric Based‐Microswimmers with Chemical and Optical Engines

Advanced Intelligent Systems, EarlyView.
Temperature sensing at small scales is typically performed using passive luminescent particles. Here, an alternative approach is demonstrated by integrating upconversion thermometry into self‐propelled microswimmers powered by chemical fuels or light. This strategy offers a step toward dynamic thermal sensing at the microscale, relevant to both lab‐on ...
João M. Gonçalves, Katherine Villa
wiley   +1 more source

Iron‐Photocatalyzed C(sp3)–H Phosphonylation of Alkanes

Angewandte Chemie, EarlyView.
Alkyl phosphonates are valuable motifs that can be prepared by phosphonylations of various common functional groups. However, direct phosphonylations of C(sp3)–H bonds are limited to activated positions. Herein, we report an iron‐photocatalyzed phosphonylation of unactivated C(sp3)–H bonds using a novel phosphite radical trap, which is equipped with an
Ya Dong, Wangyujing Han, Hanwen Zhang, Santosh K. Pagire, Harry Meats, Adam Noble, Varinder K. Aggarwal   +6 more
wiley   +2 more sources

Inhibition of Photocatalyst‐Assisted Electron Transfer at ITIES Under Simulated Solar Irradiation‐the Role of Supporting Electrolyte

ChemElectroChem
Photocatalyst‐assisted charge transfer at the interface between two immiscible electrolyte solutions (ITIES) has been previously proven. However, its practical application requires information on its performance under solar irradiation.
Edwin Avella, Andrea Folli, Angel Cuesta
doaj   +1 more source

Effects of Ohmic Contact Formation between GaN Photocatalyst and Pt Cocatalyst

Electrochemistry
A model photocatalyst composed of n-type GaN thin film as a photocatalyst body with a comb shaped electrode composed of Pt layer or Pt/Ti bilayer on the surface was successfully prepared, and photocatalytic and electric properties are investigated ...
Takaya OCHIAI, Meita ASAMI, Lionel VEIGA, Shingi YAMAGUCHI, Masakazu SUGIYAMA, Tsutomu MINEGISHI   +5 more
doaj   +1 more source