A two‐step process was transferred from batch to flow mode for the synthesis of (R)‐2‐fluoro‐1‐phenylethanol as a benchmark, consisting of a decarboxylative fluorination in aqueous media, followed by an enantioselective biocatalytic reduction of the prochiral intermediate with RrADH immobilized on silica supraparticles.
Egzon Cermjani +7 more
wiley +1 more source
Current Research on MoS<sub>2</sub>-Based Heterojunction Photocatalysts for Persistent Organic Pollutants Degradation. [PDF]
Isac L, Cazan C.
europepmc +1 more source
Simultaneous removal of estrogens and pathogens from secondary treated wastewater by solar photocatalytic treatment [PDF]
Chatzisymeon, E. +4 more
core
A strategy for the Pt/TiO2‐photocatalyzed β‐scission of nonactivated 3° alcohols in the absence of external oxidants and additives was developed. A wide variety of C‐centered radicals were generated and subsequently engaged in C─C bond‐forming reactions.
Shu Sakurai +3 more
wiley +1 more source
Photochemical reduction of aryl chlorides, bromides, and iodides <i>via</i> ternary EDA complexes with guanidine bases. [PDF]
Hannan RJ +7 more
europepmc +1 more source
Generation of a Ground‐State Electron Donor Utilizing Stored Light Energy
Chemically stored light energy enables the generation of dianion reductants (∼−2.7 V) from vicinal diols derived from diaryl ketone photodimerization. These ground‐state electron donors efficiently reduce challenging substrates at room temperature, including aryl bromides, alkyl iodides, and sulfonamides.
Marc Taillefer +2 more
wiley +1 more source
Reduced graphene oxide promoted by SnO<sub>2</sub> for photodegradation of tetracycline in water. [PDF]
Bahrami A, Mohammadi D, Akhlaghian F.
europepmc +1 more source
Asymmetric Reduction of Unactivated Alkenes
Unactivated alkenes rank among the most inert functional groups in synthesis and their selective reduction remains challenging. This Review charts the evolution from classical metal‐catalyzed hydrogenation to radical hydrogen atom transfer (HAT) and emerging biocatalytic concepts, highlighting how complementary mechanistic strategies, including the ...
Nico D. Fessner +3 more
wiley +1 more source
Cooperative NHC and Photoredox Dual Catalysis for the Construction of Carbonyl Compounds. [PDF]
Dhayalan V.
europepmc +1 more source
Insights into the Photocatalytic Arene Bromination Enabled by Cs2AgBiBr6 Microparticles
A sustainable photocatalytic bromination of electron‐rich arenes is enabled by low‐toxicity Cs2AgBiBr6 double‐perovskite microparticles using HBr as an atom‐economical bromine source. Surface‐derived bromine radicals drive highly selective mono‐bromination under mild conditions.
Daniele Conelli +8 more
wiley +1 more source

