Results 151 to 160 of about 54,561 (311)

Light‐Activated Ruthenium Nanoclusters Reprogram the Metabolic‐Quorum Sensing Axis for Precision Periodontitis Therapy

open access: yesAdvanced Science, EarlyView.
Under 660 nm visible light, Ru NCs efficiently photocatalyze nitrate‐to‐ammonium conversion and modulate oral nitrogen metabolism. They precisely perturb Veillonella parvula, block its key support to Porphyromonas gingivalis, and exert an “inhibiting without killing” antivirulence effect.
Jing Zhou   +10 more
wiley   +1 more source

A combined photolytic–electrolytic system for the simultaneous recovery of copper and degradation of phenol or 4-chlorophenol in mixed solutions

open access: yes, 2008
The effects of the presence of copper on the photooxidation of phenol and 4-chlorophenol and of the presence of the phenols on the recovery of copper by electrodeposition are studied in three systems: a photolytic cell in the presence and absence of TiO2
Grimes, SM, Chaudhary, AJ
core  

Metal Ion‐Induced Fast Gelation of 2D MnO2 Nanosheets With Cationic Vacancies for Durable Aqueous Zinc‐Ion Batteries

open access: yesAdvanced Science, EarlyView.
We report Mn‐deficient aerogels by inducing the first gelation of MnO2 nanosheets in solution using divalent metal ions as crosslinking agents, thereby inhibiting nanosheet restacking and enhancing surface utilization. Benefiting from abundant Mn vacancies and 3D porous structures, the A‐MnO2 cathode exhibits improved conductivity, fast reaction ...
Yalei Wang   +6 more
wiley   +1 more source

Mesoporous Catalytic‐Adsorptive Nanoregulator Orchestrates Biofilm eDNA/LPS Disassembly and TLR9/TLR4 Immune Reprogramming to Resolve Diabetic Foot Infections

open access: yesAdvanced Science, EarlyView.
Chronic diabetic wounds are hindered by a “dual trap” of biofilm resistance and hyperinflammation. A mesoporous catalytic‐adsorptive nano‐regulator is developed to dismantle this barrier through simultaneous eDNA degradation and LPS sequestration. By silencing TLR4/9‐mediated signaling, the platform clears resilient pathogens and reprograms the immune ...
Junfeng Song   +10 more
wiley   +1 more source

Mechanochemistry Meets Catalysis: Metal Complexes for Greener Organic Transformations

open access: yesAngewandte Chemie, EarlyView.
Mechanochemistry is redefining metal catalysis by controlling catalyst formulation, speciation, and deployment. This Review shows how milling, LAG, RAM, and TSE enable rapid metal‐complex assembly, distinctive catalytic manifolds, and scalable synthesis beyond solution chemistry.
Sourav Behera   +2 more
wiley   +2 more sources

Theoretical investigation on the adsorption configuration and (OH)-O-center dot-initiated photocatalytic degradation mechanism of typical atmospheric VOCs styrene onto (TiO2)(n) clusters

open access: yes, 2015
In this study, the adsorption mechanism and hydroxyl radical ((OH)-O-center dot)-initiated photocatalytic degradation mechanism of styrene onto different (TiO2)(n) clusters were investigated using density functional theory.
Ji, Yuemeng   +4 more
core   +1 more source

Dual Impact of Long‐Lived Localized Carriers Induced by Restricted Hole Transfer in Organic Photovoltaics and Photocatalytic Hydrogen Evolution

open access: yesAdvanced Energy Materials, EarlyView.
This work clarifies why organic semiconductors perform differently in photovoltaic devices and photocatalytic nanoparticles. By examining D18:Y5 and PM6:Y6 systems, we show how aggregation, exciton lifetime, and interfacial charge transfer behavior govern energy‐conversion pathways.
Gayoung Ham   +14 more
wiley   +1 more source

Synergistic Lewis Acid Photocatalysis Over Cluster‐Defect‐Engineered UiO‐66 for Efficient Liquid Biomass Upgrading

open access: yesAngewandte Chemie, EarlyView.
A cluster‐defect engineering strategy is presented for the rational design of Zn‐incorporated UiO‐66 photocatalysts. Selective acid etching mediates hierarchical porosity and abundant Lewis acid sites, tailoring the electronic structure and enhancing light harvesting.
Hao Wang   +6 more
wiley   +2 more sources

Photocatalytic degradation of 2-(4-methylphenoxy)ethanol over TiO2 spheres

open access: yes, 2017
The photocatalytic TiO2-assisted decomposition of 2-(4-methylphenoxy)ethanol (MPET) in aqueous solu-tion has been studied for the first time. The intermediate compounds of MPET photodegradation havebeen also determined.
Díaz Eva, Amghouz Zakariae   +2 more
core  

Photothermally Enhanced Hydrogel‐Based Thermoelectrochemical Cells for Stable, Passive Harvesting of Low‐Grade Heat

open access: yesAdvanced Energy Materials, EarlyView.
A photothermally enhanced hydrogel‐based thermoelectrochemical cell enables passive conversion of low‐grade heat and solar energy into electricity. The quasi‐solid device achieves high thermopower and stable long‐term operation under passive conditions.
Matteo Bevione   +2 more
wiley   +1 more source

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