Results 201 to 210 of about 126,801 (303)

Homoleptic and Heteroleptic Carbones L1‐C‐L2

open access: yesAngewandte Chemie, EarlyView.
DFT and CCSD(T) calculations reveal that heteroleptic carbones L₁–C–L2 are thermodynamically stable species even with a weakly binding donor such as N2. Bond strengths show no simple correlation with bond lengths. Weaker carbon‐ligand bonds in homoleptic complexes L1─C─L1 are mostly strengthened in heteroleptic carbons L1─C─L2, while stronger bonds L2 ...
Ya Hu   +4 more
wiley   +1 more source

Thermo-Photochemistry

open access: yesCHIMIA, 1989
Augustin J. McEvoy   +4 more
doaj   +1 more source

Disrupting the Photochemical Landscape of a β-Diketone via Electrostatic Perturbation of Ground-State Tautomers. [PDF]

open access: yesJ Am Chem Soc
Anstöter CS   +6 more
europepmc   +1 more source

Dithioketal Polymers Via Radical Polymerization of γ‐Dithiobutyrolactone

open access: yesAngewandte Chemie, EarlyView.
γ‐Dithiobutyrolactone (DTBL) behaves like a ring‐retaining monomer in radical copolymerization with a series of conjugated monomers like styrene, t‐butyl acrylate and N,N‐dimethylacrylamide. The resulting copolymers contain controlled fractions of dithioketal linkages in their backbone, allowing chemical degradation.
Maksym Odnoroh   +5 more
wiley   +1 more source

Excited-State Chemistry of Hydroperoxymethyl Thioformate in the Troposphere. [PDF]

open access: yesJ Phys Chem A
Catalán-Fenollosa D   +5 more
europepmc   +1 more source

Merging Biocatalysis and Chemocatalysis in Flow: State‐of‐the‐Art and Future Directions for Sustainable Synthesis

open access: yesAngewandte Chemie, EarlyView.
This review highlights recent advances in integrating biocatalysis and chemocatalysis in continuous flow to create streamlined, sustainable processes. It examines chemo‐enzymatic cascades combining at least one enzymatic and one chemical step, discusses challenges such as enzyme immobilization, leaching, and reactor clogging, and presents solutions ...
Petros Siasiaridis   +2 more
wiley   +1 more source

Converting 1,1‐Bisborylalkanes into 1,2‐Bisborylalkanes Enabled by Iron Ligand‐to‐Metal Charge Transfer (LMCT) Photocatalysis

open access: yesAngewandte Chemie, EarlyView.
1,2‐Bisborylalkanes are valuable intermediates for chemical synthesis as they could serve as a platform to generate value‐added products with two distinct functional groups at vicinal positions. A novel strategy to synthesize 1,2‐bisborylalkanes via Fe ligand‐to‐metal charge transfer (LMCT) photocatalysis is developed.
Zheye Zhang   +5 more
wiley   +1 more source

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