Rapid Detection of Plasticizer Migration From UV‐Aged PVC Films by DART‐HRMS
ABSTRACT Rationale The migration of phthalate plasticizers from high‐volume polymers, such as poly(vinyl chloride) (PVC), raises significant toxicological concerns, particularly when materials are subjected to aging and environmental stress. As traditional monitoring techniques rely on time‐consuming solvent extraction and chromatographic methods that ...
Odilon Leite‐Barbosa +4 more
wiley +1 more source
Mechanism of the Photodecomposition of Stable Triarylmethyl Radicals
Photolysis of luminescent chlorinated trityl radicals was studied with density functional theory and the decomposition products were isolated and characterized. It proceeds by a 5‐electron electrocyclization then a 1,8‐sigmatropic chloride shift, forming non‐emissive, less stable fluorenyl radicals.
Hannah E. Hackney +3 more
wiley +2 more sources
Surface Modification of TiO<sub>2</sub> Nanorods for Dye Removal: Photodegradation vs Adsorption Activity. [PDF]
Lo Porto C +6 more
europepmc +1 more source
Polyolefin encapsulants are gaining dominance in PV modules, yet confusion persists around PO, POE, and TPO definitions. This study clarifies terminology, reviews materials, and properties and proposes a taxonomy to improve understanding, communication, and reliability in solar module manufacturing.
Gernot Oreski +14 more
wiley +1 more source
The Effect of UV Exposure on Selected Surface Parameters of Wood Containing Graphene Oxide. [PDF]
Betlej I +4 more
europepmc +1 more source
Relative Humidity Influences Aureobasidium pullulans Degradation of Polyester Polyurethane Foam
The plant pathogen Aureobasidium pullulans' ability to degrade polyurethane foam is impacted by Equilibrium Relative Humidity (ERH). These impacts can be observed through foam weight loss, scanning electron microscopy (SEM), fungal growth, and cutinase gene expression.
Amanda Stickney +8 more
wiley +1 more source
Acid‐ and Nucleophile‐Gated Photoisomerization of Phosphaindirubin
Triply gated isomerization: In polar solvents, a phosphorus‐containing indirubin photoswitch undergoes visible‐light‐driven Z→E isomerization only when protonated, and reverts thermally via nucleophile‐catalyzed back‐isomerization. This three‐way control by light, acid, and nucleophile enables reversible photoisomerization.
Jacob Jan van der Wal +8 more
wiley +2 more sources
Ferroelectric-assisted BaTiO<sub>3</sub>/Cr-Zr-HMS (5, 10 & 20) catalysts for efficient visible-light removal of bromocresol green: structure-activity relationship and process optimization. [PDF]
Parsafard N, Asgharinezhad AA, Karami N.
europepmc +1 more source
Facet-dependent Heterogeneous Fenton Reaction Mechanisms on Hematite Nanoparticles for (Photo)catalytic Degradation of Organic Dyes. [PDF]
Chen P +15 more
europepmc +1 more source
Photodegradation of diclofenac in aqueous media <i>via</i> a HO˙ radical pathway using CeO<sub>2</sub>/g-C<sub>3</sub>N<sub>4</sub> heterojunction under visible light: experimental and computational insights. [PDF]
Van Do D +5 more
europepmc +1 more source

