Photochemical Cyclization of Tertiary Buta‐2,3‐dienamides to β‐Lactams Upon Triplet Energy Transfer
Energy transfer is the key to the successful photocyclization of the title compounds to 3,4‐disubstituted 2‐azetidinones. If the substituent at the nitrogen atom is primary (R2 = H), trans products are formed exclusively. The triplet state of xanthen‐9‐one (XT) was found to be quenched by an allene amide (R, R2 = H, R1 = Bn, and R3 = Ph) with a ...
Johannes Hofer +3 more
wiley +2 more sources
Green synthesis of CoAl2O4@ZnO nanocomposite using Aamygdalus scoparia Spach gum and its photocatalytic activity for tetracycline degradation. [PDF]
Nejadkhorasani F +2 more
europepmc +1 more source
Relative Humidity Influences Aureobasidium pullulans Degradation of Polyester Polyurethane Foam
The plant pathogen Aureobasidium pullulans' ability to degrade polyurethane foam is impacted by Equilibrium Relative Humidity (ERH). These impacts can be observed through foam weight loss, scanning electron microscopy (SEM), fungal growth, and cutinase gene expression.
Amanda Stickney +8 more
wiley +1 more source
Introduction of Periodic Ketone Units on Vinyl Polymers via a Radical Alternating Copolymerization and Postpolymerization Modification: Sequence-Oriented Photodegradation in the Bulk State. [PDF]
Kuroda K, Ouchi M.
europepmc +1 more source
ABSTRACT Glomerella leaf spot (GLS), a fungal disease caused by Colletotrichum fructicola, is a major destructive disease of apples but research on control measures is limited. Melatonin (MT) is a phytohormone‐like compound that affects plant growth and stress response but is prone to light‐induced degradation, resulting in low stability and efficacy ...
Yong Zhang +7 more
wiley +1 more source
Manganese (III) meso-tetrakis(4-nitrophenyl) porphyrin sensitizes TiO₂ nanoparticles into visible region via a pyridyl linker for degradation of organic dyes. [PDF]
Rezaei M +3 more
europepmc +1 more source
Mechanism of the Photodecomposition of Stable Triarylmethyl Radicals
Photolysis of luminescent chlorinated trityl radicals was studied with density functional theory and the decomposition products were isolated and characterized. It proceeds by a 5‐electron electrocyclization then a 1,8‐sigmatropic chloride shift, forming non‐emissive, less stable fluorenyl radicals.
Hannah E. Hackney +3 more
wiley +2 more sources
Enhancement of commercial dye photocatalytic degradation through the use of silver-doped kaolinite-zinc oxide quantum dots. [PDF]
Farrag AM +3 more
europepmc +1 more source
Titania-Supported Photocatalytic Coatings of Cu<sub>2</sub>O Nanoparticles Synthesized via Heterogeneous Nucleation. [PDF]
Demény P +10 more
europepmc +1 more source
We report the synthesis bis(arylethynyl)naphtho‐ and anthraquinones via Rh(I)‐catalyzed [2 + 2 + 2] cycloaddition reactions. The substrate scope of both quinones and linked bis‐diynes was explored. Microwave irradiation remarkably enhanced yields.
Luana A. Machado +16 more
wiley +1 more source

