Results 31 to 40 of about 20,014 (223)

Preparing sulfur nanoparticles and determining their effect on the photodegradation of polycarbonates [PDF]

open access: yesمجلة جامعة الانبار للعلوم الصرفة
This study involved the preparation of sulfur nanoparticles using the extract of Ziziphus-spina leaves and examined their effect on the photodegradation of polycarbonate membranes with a thickness of (60±5) microns, after adding various ...
rand hassan, Hameed Ali, Muthanaa Sirhan
doaj   +1 more source

Measurement of the Photodissociation Coefficient of NO2 in the Atmosphere: II. Stratospheric Measurements [PDF]

open access: yes, 1985
The photodissociation coefficient of NO2, J NO 2, has been measured from a balloon platform in the stratosphere. Results from two balloon flights are reported.
Madronich, S.   +3 more
core  

Photodissociation dynamics of ketene at 157.6 nm

open access: yes, 2006
Photodissociation dynamics of ketene at 157.6 nm has been investigated using the photofragment translational spectroscopic technique based on photoionization detection using vacuum-ultraviolet synchrotron radiation.
Yang, XM   +4 more
core   +1 more source

On Metal Carbonyl Compounds in Catalytic Methanol Synthesis: Detection, Consequences, and Removal

open access: yesChemie Ingenieur Technik, EarlyView.
Deactivation of Cu/ZnO/Al2O3 catalysts by metal carbonyl compounds in the feed gas is a critical problem in catalytic methanol synthesis. We utilize PTR–MS to identify potential chemical sources, detect contamination in an in‐house CO gas line, and validate filter methods for removing these catalyst poisons before synthesis.
Florian Stappert   +4 more
wiley   +1 more source

Photostop [PDF]

open access: yes, 2013
The use of photodissociation to produce cold, slow molecules from a molecular beam of cold, fast molecules is dubbed “photostop”. The essence of the scheme is thus: a pulsed molecular beam of a precursor molecule AB seeded in a noble carrier gas is ...
ROWLAND, ADRIAN,MURRAY
core  

Confined Hot Carrier Cooling Via Excited‐State Energy Gap Engineering in Graphyne Carbon Allotropes

open access: yesENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The excited‐state energy gap (EEG), regulated by the concentration of sp‐hybridized carbon, provides an effective handle for tuning electron–phonon coupling behavior. This design enables long‐lived confinement of hot carriers near the top of the EEG with controllable energy levels.
Fulong Dai   +9 more
wiley   +1 more source

Exploring the energy disposal immediately after bond-breaking in solution:the wavelength-dependent excited state dissociation pathways of para-methylthiophenol [PDF]

open access: yes, 2013
A wavelength-resolved (λpump = 295, 285, 270, and 267 nm) photodissociation study of para-methylthiophenol (p-MePhSH) in ethanol solution has been performed using femtosecond transient absorption (TA) spectroscopy, and the results compared with those ...
Das, Saptaparna   +5 more
core   +1 more source

Kinetic Study on the Reaction of Phenylperoxy Radicals With Nitric Oxide

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT Cavity ring‐down spectroscopy (CRDS) and quantum cascade laser absorption spectroscopy (QCLAS), in conjunction with pulsed laser photolysis, were employed to investigate the reaction between phenylperoxy radicals (C6H5O2) and nitric oxide (NO) at a temperature of 296 ± 4 K. The experiment was carried out under N2 as bath gas.
Maya Matsushita   +2 more
wiley   +1 more source

PHOTODISSOCIATION OF PbCl2

open access: yesActa Physica Sinica, 1988
The population on 6p2 3P2 metastable state and 6p2 3P0 ground state of Pb atoms are de-monstrated, which are originated from dissociating PbCl2 by the fourth harmonic of YAG lasers. The population ratio of 3P2 to 3P0 is measured in terms of laser-induced fluorescence.
null ZHANG JIE   +5 more
openaire   +1 more source

Cis–Trans Rotational Isomerism of Formic Acid, Sulfur, and Selenium Analogues and Their Dimers: Chemical Kinetics Under Interstellar Conditions

open access: yesInternational Journal of Chemical Kinetics, EarlyView.
ABSTRACT We present chemical kinetic rate constants for the cis to trans isomerisation or rotamerization of monomeric seleno‐, thio‐, and formic acids and that of three of their dimeric species, based on variational transition state theory and multidimensional tunneling calculations in the gas‐phase, from 10 K to 300 K. These provide, firstly, reliable
Judith Wurmel, John M. Simmie
wiley   +1 more source

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