Results 171 to 180 of about 26,931 (258)

Rapid Joule‐Heating‐Induced Non‐Equilibrium Exsolution in Perovskite Oxides for Enhanced Photothermal CO2 Methanation

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Rapid Joule heating induces Ni—Fe exsolution from perovskite oxides, forming Ni–Fe/oxide heterointerfaces that enhance photothermal CO2 methanation activity and selectivity. Achieving selective CO2 methanation under photothermal conditions requires catalysts capable of maintaining non‐equilibrium interfacial states that balance reduction and oxidation ...
Qiankai Zhang, Qinghao Li, Kaiyue Xing, Gan Jin, Lei Fu, Le Shi, Yang Wang, Junbo Wang, Kai Wu, Jun Zhou   +9 more
wiley   +1 more source

d‐Orbital Electron Spin Polarization Field Inhibits Photo‐Generated Carrier Recombination for Panel Photoelectrocatalysis

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A solution‐processable sub‐nanocrystal of metal coordinated conjugated reticular oligomer with spin polarization functionality is employed as an active layer in planar photoelectrochemical water splitting. The rapid recombination of photo‐generated carriers remains a critical challenge limiting the photo‐electrocatalytic water splitting performance in ...
Ruijuan Zhang, Jiaqi Lv, Yue Wang, Xianghao Meng, Yali Yao, Xinying Liu, Shanlin Qiao   +6 more
wiley   +1 more source

Surface‐Strongly Complexed BiVO4 Homojunction Photoanodes: Enabling Efficient Antibiotic Pollutant Degradation and Resource Upgrading

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Herein, a synergistic photoelectrochemical‐photothermal platform is constructed for simultaneous kanamycin remediation and resource valorization, addressing energy and environmental concerns. Photoelectrochemical (PEC) technology offers a promising approach for degrading antibiotic pollutants, yet it remains constrained by low efficiency and incomplete
Zhaoqi Wang, Yaqi He, Xiaolei Liu, Zaizhu Lou, Difei Xiao, Peng Wang, Zhaoke Zheng, Yuanyuan Liu, Hefeng Cheng, Baibiao Huang, Zeyan Wang, Dongqi Tang   +11 more
wiley   +1 more source

Precisely Constructed Asymmetric Coordination Tuned High‐Spin Co Sites for Sacrificial Agent‐Free H2O2 Photocatalytic Production

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The asymmetric Co–N2O2 coordination structure was precisely constructed through the assembly of Salen COF. The high‐spin (t2g4eg3$$ {\mathrm{t}}_{2\mathrm{g}}^4{\mathrm{e}}_{\mathrm{g}}^3 $$) Co center enables Pauling‐type O2 adsorption, inhibiting the cleavage of the O–O bond. π‐d conjugation enhances charge separation and transport.
Wenhui Qi, Shaonan Gu, Yinan Wang, Wenhao Yin, Bin Sun, Guowei Zhou   +5 more
wiley   +1 more source

Integrated Solvent‐Catalyst‐Dopant Strategy via Acidic DES for Synthesizing Lignin‐Derived Carbon Dots With High‐Quantum Yield to Achieve Efficient Photocatalytic Degradation of Tetracycline

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A deep eutectic solvent (ChCl/pTSA) platform enables integrated solvent, catalyst, and dopant functions, producing sulfur‐doped carbon quantum dots with a high sp2‐C content (82.8%) and a quantum yield of 56.9%. When combined with TiO2, the CQDs form TiOC and TiOS interfacial bridges, achieving 97.3% tetracycline photodegradation with excellent ...
Xinhang Li, Haipeng Guo, Suen Hou, Fenghua Huang, Hailong Yu   +4 more
wiley   +1 more source

Oxygen Vacancy‐Rich S‐Scheme Heterojunction Photocatalyst With Enhanced Interfacial Charge Transfer for Round‐the‐Clock Formaldehyde Degradation

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
This work addresses the critical challenges of severe charge recombination and the dependence on constant light illumination in photocatalysis. We propose a strategy centered on an oxygen vacancy‐rich S‐scheme heterojunction, which enables precise regulation of charge carrier behavior and achieves long‐lasting photocatalytic performance.
Xuechuan Wang, Zhi Zhao, Xiaoyu Guan, Ji Li, Chuanyin Xiong, Taotao Qiang, Qingxin Han   +6 more
wiley   +1 more source

Cobalt Single‐Atom Sites Engineered in Poly(Heptazine Imide) Photocathodes as Benchmark for Alkaline Hydrogen Evolution: A Comparative Transition Metal Study

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Cobalt single‐atoms in poly(heptazine imide) photocathodes maximize active‐site availability and outperform Fe, Cu, and Na in alkaline hydrogen evolution. Atomic precision (not bulk loading) proves predominance, establishing a design principle for the next generation of solar fuel devices.
Izadora F. Reis, Gabriel A. A. Diab, Sachin Nenaniya, Marcos A. R. da Silva, Rayse M. Ferreira, Heer Shah, Geraldo M. G. da Silva, Andreas Hutzler, Mark Isaacs, Christian W. Lopes, Ivo F. Teixeira, Pablo Jiménez‐Calvo   +11 more
wiley   +1 more source

Polarization‐Reoriented Piezocatalysis Enables Plastic Upcycling with Mechanical Energy

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Mixed plastic waste remains difficult to upcycle selectively under mild conditions, and piezocatalysis has been constrained by a persistent see‐saw effect: Stronger piezoelectric polarization tends to divert charge carriers away from the very active sites that drive catalysis. Sha et al.
Tao Chen, Tian Liang, Zhongxiang Wang
wiley   +1 more source

Recent Progress of Metal Halide Perovskite‐Based S‐Scheme Heterojunction for Solar Energy Conversion

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Recent advances in metal halide perovskite‐based S‐scheme photocatalytic heterojunctions are systematically reviewed in this work. Synthetic protocols, state‐of‐the‐art characterizations for tracking interfacial charge transfer, and their diverse photocatalytic applications are thoroughly explored.
Xinhe Wu, Shujie Yin, Jiachao Xu, Lihong Tan, Guohong Wang   +4 more
wiley   +1 more source

Selective N‐Functionalization of Pyrazoles

European Journal of Organic Chemistry, EarlyView.
This review traces the evolution of regioselective N‐functionalization strategies for pyrazoles, a key class of nitrogen heterocycles widely used in medicinal chemistry. Due to rapid tautomerism, N‐functionalization often lacks selectivity, leading to poor and unpredictable regioisomeric outcomes.
Lucas Popek, Matthias Schrader, Christopher J. Teskey   +2 more
wiley   +1 more source