Results 221 to 230 of about 49,559 (307)
Green Emissions of Atomic Oxygen at Sprite Tops Explained
Abstract Green emissions from excited Oxygen in Sprite Tops (GhOSTs) are due to the 557 nm photons emitted from atomic oxygen (O) $(\mathrm{O})$ excited to the 1S state. In this work we compare the possible contribution of various mechanisms for excitation of O(S1) $\mathrm{O}({}^{1}S)$ under application of a lightning‐induced electric field to the ...
Brandon Smith +2 more
wiley +1 more source
Light-Induced Orthogonal Reactivity of Photoinitiators from One-Electron Reduction to Nanocomposites. [PDF]
Schmallegger M, Wiech M, Gescheidt G.
europepmc +1 more source
Abstract Biomass burning aerosol (BBA) impacts climate through aerosol‐cloud‐radiation interactions, but models disagree on the sign and magnitude of BBA radiative effects. We quantify the sensitivity of BBA radiative effects and transport to three BBA‐relevant processes and properties: parameterized oxidative aging of organic aerosol (OA), a combined ...
Kate Johnson +9 more
wiley +1 more source
From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk +4 more
wiley +2 more sources
Proton-Coupled Electron Transfer in Cytochrome c Oxidase: Heme a Controls the Protonation Dynamics of E286. [PDF]
Baserga F +5 more
europepmc +1 more source
Heterogeneous Iodine Chemistry Impacts Reactive Halogen and Oxidant Abundances
Abstract Tropospheric reactive halogens influence the oxidizing capacity of the atmosphere. Although previous studies have shown that iodine exerts the strongest impact on tropospheric ozone concentrations compared to chlorine and bromine, the impact of aerosol iodide recycling back to the gas phase on oxidants has not been estimated prior to this work.
Allison R. Moon +22 more
wiley +1 more source
A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi +9 more
wiley +2 more sources
OH-Initiated Photooxidation of Gas-Phase Atmospherically Relevant Monoterpene-Derived Organic Nitrates. [PDF]
Wang Y +4 more
europepmc +1 more source
MnCl2‐Catalyzed Photochemical Functionalization of Unactivated C(sp3)H Bonds
A photochemical method enables the activation of alkanes, utilizing cheap and abundant MnCl2 as the photocatalyst. Alkenylation and alkylation reactions are performed, affording the desired products in good yields. Activation of inert C(sp3)H bonds is of great importance in organic synthesis, since it can functionalize unreactive molecules, such as ...
Naya A. Stini +3 more
wiley +1 more source
Photolysis of CO2 Carbamate for Hydrocarboxylation Reactions. [PDF]
Azzi E +5 more
europepmc +1 more source

