Results 221 to 230 of about 49,559 (307)

Green Emissions of Atomic Oxygen at Sprite Tops Explained

open access: yesGeophysical Research Letters, Volume 53, Issue 11, 16 June 2026.
Abstract Green emissions from excited Oxygen in Sprite Tops (GhOSTs) are due to the 557 nm photons emitted from atomic oxygen (O) $(\mathrm{O})$ excited to the 1S state. In this work we compare the possible contribution of various mechanisms for excitation of O(S1) $\mathrm{O}({}^{1}S)$ under application of a lightning‐induced electric field to the ...
Brandon Smith   +2 more
wiley   +1 more source

Strong Sensitivity of Simulated Biomass Burning Aerosol Transport and Radiative Effects Over the South Atlantic to Carbonaceous Aerosol Aging and Particle Density

open access: yesJournal of Geophysical Research: Atmospheres, Volume 131, Issue 11, 16 June 2026.
Abstract Biomass burning aerosol (BBA) impacts climate through aerosol‐cloud‐radiation interactions, but models disagree on the sign and magnitude of BBA radiative effects. We quantify the sensitivity of BBA radiative effects and transport to three BBA‐relevant processes and properties: parameterized oxidative aging of organic aerosol (OA), a combined ...
Kate Johnson   +9 more
wiley   +1 more source

From [NHC─H]• to Persistent σ‐Complex Radicals: Photoinduced Radical Chemistry of Imidazolium Salts

open access: yesAngewandte Chemie, Volume 138, Issue 24, 8 June 2026.
Visible‐light excitation of electron donor–acceptor (EDA) complexes between imidazolium salts and triarylamines enables controlled single‐electron transfer (SET) and reveals a family of carbene‐centered σ‐complex radical cations. Cryogenic electron paramagnetic resonance (EPR) captures the elusive [NHC─H]• intermediate and its thermal evolution into ...
Filipp M. Kolomeychuk   +4 more
wiley   +2 more sources

Heterogeneous Iodine Chemistry Impacts Reactive Halogen and Oxidant Abundances

open access: yesGeophysical Research Letters, Volume 53, Issue 11, 16 June 2026.
Abstract Tropospheric reactive halogens influence the oxidizing capacity of the atmosphere. Although previous studies have shown that iodine exerts the strongest impact on tropospheric ozone concentrations compared to chlorine and bromine, the impact of aerosol iodide recycling back to the gas phase on oxidants has not been estimated prior to this work.
Allison R. Moon   +22 more
wiley   +1 more source

Site‐Selective B─H Activation via HAT Toward Xanthyl‐closo‐Carboranes as Bench‐Stable Precursors of Organosulfur Boron Clusters

open access: yesAngewandte Chemie, Volume 138, Issue 24, 8 June 2026.
A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi   +9 more
wiley   +2 more sources

MnCl2‐Catalyzed Photochemical Functionalization of Unactivated C(sp3)H Bonds

open access: yesChemSusChem, Volume 19, Issue 11, 15 June 2026.
A photochemical method enables the activation of alkanes, utilizing cheap and abundant MnCl2 as the photocatalyst. Alkenylation and alkylation reactions are performed, affording the desired products in good yields. Activation of inert C(sp3)H bonds is of great importance in organic synthesis, since it can functionalize unreactive molecules, such as ...
Naya A. Stini   +3 more
wiley   +1 more source

Photolysis of CO2 Carbamate for Hydrocarboxylation Reactions. [PDF]

open access: yesJ Am Chem Soc
Azzi E   +5 more
europepmc   +1 more source

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