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Organic Photoredox Catalysis

Chemical Reviews, 2016
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic transformations with a range of applications. This overview is arranged by catalyst class where the photophysics and electrochemical characteristics of each is discussed to underscore the differences and advantages to each type of single electron redox agent ...
Nathan A, Romero, David A, Nicewicz
openaire   +2 more sources

Cooperative photoredox catalysis

Chemical Society Reviews, 2016
Cooperative photoredox catalysis bridges visible-light photoredox catalysis with other types of catalysis like transition-metal catalysis, biocatalysis or electrocatalysis for establishing demanding organic transformations.
Xianjun, Lang   +2 more
openaire   +2 more sources

Illuminating Photoredox Catalysis

Trends in Chemistry, 2019
Over the past decade, photoredox catalysis has risen to the forefront of synthetic organic chemistry as an indispensable tool for selective small-molecule activation and chemical-bond formation. This cutting-edge platform allows photosensitizers to convert visible light into chemical energy prompting generation of reactive radical intermediates.
Rory C, McAtee   +2 more
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A Borocarbonitride Ceramic Aerogel for Photoredox Catalysis

Angewandte Chemie - International Edition, 2019
AbstractBorocarbonitride (BCN) is a new type of photocatalyst, but bulk BCN shows a large band gap, and low surface area, and moderate activity for photocatalysis. Here, a three‐dimensional (3D) porous ceramic BCN aerogel was developed as an effective photocatalyst for relevant reactions.
Fang Yuanxing, Xinchen Wang, Min Zhou
exaly   +3 more sources

Syntheses of functionalized benzocoumarins by photoredox catalysis

Organic & Biomolecular Chemistry, 2023
We report a new method for the synthesis of functionalized benzocoumarins through the strategy of activation of multiple C–H bonds on 2-aryl toluenes under visible-light-enabled photoredox conditions.
Qihong Lai   +7 more
openaire   +2 more sources

The forgotten reagent of photoredox catalysis

Dalton Transactions, 2022
Light is a critical reagent in photochemical synthesis but rarely considered beyond on or off controls. This Frontier article highlights recent examples where photon delivery is controlled, affording unique reactivity.
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Visible‐Light Photoredox Catalysis

Angewandte Chemie International Edition, 2012
AbstractIn the last few years, visible‐light initiated organic transformations have attracted increasing attention. The development of visible‐light‐promoted photocatalytic reactions, which enable rapid and efficient synthesis of fine chemicals, is highly desirable from the viewpoint of cost, safety, availability, and environmental friendliness.
Jun, Xuan, Wen-Jing, Xiao
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Organic Photoredox Catalysis

2022
Organic photoredox catalysis is a powerful light-driven synthetic technology enabling the development of a diverse number of organic free radical reactions. It has had a substantial impact on organic synthesis, materials science and pharmaceutical chemistry and will be an essential method for looking at future research developments.
Hans-Achim Wagenknecht, Todd Hyster
openaire   +1 more source

Enantioselective palladium photoredox catalysis

Chemical Communications
The merger of visible light and transition metal catalysis, particularly palladium catalysis, has unlocked new opportunities and challenges in asymmetric synthesis.
Sheng Tang   +3 more
openaire   +2 more sources

Metal‐Free Carbonylations by Photoredox Catalysis

Angewandte Chemie International Edition, 2014
AbstractThe synthesis of benzoates from aryl electrophiles and carbon monoxide is a prime example of a transition‐metal‐catalyzed carbonylation reaction which is widely applied in research and industrial processes. Such reactions proceed in the presence of Pd or Ni catalysts, suitable ligands, and stoichiometric bases.
Michal, Majek, Axel, Jacobi von Wangelin
openaire   +2 more sources

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