Results 101 to 110 of about 420,590 (252)

Let There be Light! Light as an Engine and Regulator in Synthetic Cells

open access: yesAngewandte Chemie International Edition, EarlyView.
Cells are out‐of‐equilibrium systems that regulate their spatiotemporal features. In biomimetic synthetic cells, light offers a unique way for energizing and regulating events in space and time. This review explores the implementation of light‐responsive tools in synthetic cells to replicate biological functions and enable new bioinspired behaviors ...
Matthew E. Allen   +5 more
wiley   +1 more source

Boron‐Doping of a Macrocyclic Tetrafuran Framework Unveils an Expanded Porphyrinoid With Switchable (Anti)Aromaticity and Conformational Dynamics

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 23, 1 June 2026.
We disclose a novel boron macrocycle derived from the sustainable furan building block. The boraporphyrinoid exhibits a global antiaromatic ring current and dynamic conformational flexibility. Twofold reduction induces a switch to strong global aromaticity, accompanied by stiffening of the porphyrinoid backbone.
Lukas Swoboda   +6 more
wiley   +1 more source

Role of Water in Low‐Temperature CO2 Reduction at Defect‐Rich TiO2

open access: yesAngewandte Chemie International Edition, EarlyView.
Our results highlight the potential of reduced titania as a noble metal‐free CO2 activation catalyst and show the activation of CO2 on highly defective TiO2 using in situ synchrotron‐based NAP‐XPS from room temperature to 700 K. The distribution of surface intermediates can be decoded as a simultaneous population of reaction routes, revealing water (OH)
Justin Klimek   +6 more
wiley   +1 more source

An Artificial Molecular Pump Powered by Light

open access: yesAngewandte Chemie International Edition, Volume 65, Issue 23, 1 June 2026.
A minimal rotaxane‐based supramolecular system functions as a light‐powered molecular pump, capturing macrocycles from solution and concentrating them within an intramolecular compartment. Repeated azobenzene photoisomerization modulates the binding and kinetic barriers of threading and shuttling, generating a photon‐driven energy ratchet that sustains
Federico Nicoli   +7 more
wiley   +1 more source

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