Results 21 to 30 of about 146,521 (310)

Kinetics versus thermodynamics in virus capsid polymorphism [PDF]

open access: yes, 2016
Virus coat proteins spontaneously self-assemble into empty shells in aqueous solution under the appropriate physicochemical conditions, driven by an interaction free energy per bond on the order of 2-5 times the thermal energy kBT.
Sub Algemeen Theoretical Physics   +8 more
core   +1 more source

Physical organic chemistry in the making [PDF]

open access: yes, 1997
The discipline of physical organic chemistry will continue to occupy a central position in chemistry. The rapid increase in instrumentation and important theoretical developments allow the investigation of many problems of great complexity and challenge.
Engberts, J.B.F.N.
core   +1 more source

Biomimetic light-harvesting funnels for re-directioning of diffuse light

open access: yesNature Communications, 2018
Sunlight harvesting and redirection is a promising concept for sustainable energy conversion, however losses have hindered progress. Here the authors construct a simple biomimetic device which minimises losses by using reservoirs of randomly-oriented ...
Alexander Pieper   +7 more
doaj   +1 more source

λ/2 Fabry Pérot micro-resonators in single molecule spectroscopy

open access: yesEPJ Web of Conferences, 2018
Embedded in a tuneable λ/2-FabryPérot micro-resonator the radiative relaxation of a dye molecule or quantum dot can reproducibly be modified allowing to determine their quantum yield, control Förster energy-transfer or localize them with nanometer ...
Meixner Alfred J.   +4 more
doaj   +1 more source

Spin Labeling of RNA Using “Click” Chemistry for Coarse-grained Structure Determination via Pulsed Electron-electron Double Resonance Spectroscopy

open access: yesBio-Protocol, 2021
Understanding the function of oligonucleotides on a molecular level requires methods for studying their structure, conformational changes, and internal dynamics.
Maria Vicino   +2 more
doaj   +1 more source

Simultaneous measurement of rotational and translational diffusion of anisotropic colloids with a new integrated setup for fluorescence recovery after photobleaching [PDF]

open access: yes, 2012
This paper describes an integrated setup for fluorescence recovery after photobleaching (FRAP) for determining translational and rotational Brownian diffusion simultaneously, ensuring that these two quantities are measured under exactly the same ...
van de Ven, M.C.A.   +5 more
core   +1 more source

Synthesis of Nanometer Sized Bis- and Tris-trityl Model Compounds with Different Extent of Spin–Spin Coupling

open access: yesMolecules, 2018
Tris(2,3,5,6-tetrathiaaryl)methyl radicals, so-called trityl radicals, are emerging as spin labels for distance measurements in biological systems based on Electron Paramagnetic Resonance (EPR).
J. Jacques Jassoy   +4 more
doaj   +1 more source

Understanding the Sensing Mechanism of Rh2O3 loaded In2O3

open access: yesProceedings, 2018
The effect of Rh loading on CO sensing was studied for the case of In2O3. This was done by performing measurements with sensors based on loaded and unloaded materials that were performed at an operation temperature of 300 °C in the presence of low ...
Inci Boehme   +5 more
doaj   +1 more source

Strong inverse kinetic isotope effect observed in ammonia charge exchange reactions

open access: yesNature Communications, 2020
Inverse kinetic isotope effects (KIEs) are rarely observed. Here, the authors report an inverse KIE in the charge transfer reaction of $${{\rm{Xe}}}^{+}$$ Xe+ with ammonia.
L. S. Petralia   +4 more
doaj   +1 more source

Computational physical organic chemistry using the empirical valence bond approach

open access: yes, 2019
There has been growing interest in applying the empirical valence bond approach to a range of (bio)chemical problems, primarily to study enzymatic and non-enzymatic catalysis, but also to studying other processes such as excited state chemistry and ...
Kamerlin, Shina C. Lynn,   +5 more
core   +1 more source

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