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Host-Guest Complexes of Carboxylated Pillar[ n ]arenes With Drugs
Pillar[n]arenes are a new family of nanocapsules that have shown application in a number of areas, but because of their poor water solubility their biomedical applications are limited. Recently, a method of synthesizing water-soluble pillar[n]arenes was developed.
Nial J, Wheate +8 more
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Pillar[n]arene-based Porous and Smart Materials
Pillar[n]arenes are a class of macrocycles with outstanding properties given by its electron rich and symmetric cavity, and facile functionalization that allows to tune its solubility and host-guest properties. In this work, the versatility of pillar[n]arenes for the design of porous materials is studied.
Khalil Cruz, Laila Elizabeth
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Recent development of pillar[n]arene-based amphiphiles
Chinese Chemical Letters, 2021Abstract Pillar[n]arene-based amphiphiles, mainly including amphiphilic pillar[n]arenes and supra-amphiphilic pillar[n]arenes, have obtained considerable interests in recent years due to their fascinating chemical structures, various self-assembly behaviors, and widely applications.
Yan Cai +6 more
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Supramolecular Catalysis by Carboxylated Pillar[n]arenes
ChemCatChem, 2020AbstractPillar[n]arenes constitute the most recognizable macrocyclic compounds discovered recently. So far, research has been focused on their binding properties, while the catalytic properties were poorly explored. Herein we present the study of the binding as well as the catalytic properties of pillar[5]‐ and pillar[6]arenes functionalized with ...
Sandra Kosiorek +2 more
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Advances in diversified application of pillar[n]arenes
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2020Pillar[n]arenes have become a research hotspot in recent years. Because of its unique electron-rich cavity and easy functionalization, pillar[n]arenes have been extensively studied as carrier materials for applications in materials science, life science, nanoscience, information science, intelligent science and other fields.
Liying Guo +4 more
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Perethylated pillar[n]arenes versus pillar[n]arenes: theoretical perspectives
Journal of Molecular Modeling, 2019In this article we obtain the electronic structure, 1H NMR, and the vibrational spectra of perethylated pillar[n]arene (EtPn) (n = 5-8, 10) macrocycles using the ωB97x-based density functional theory. A single cavitand structure endowed with the robust pillar-like architecture was derived for the EtPn (n = 5-7) hosts while for the EtP8 receptor, two ...
Sulakshana V. Athare, Shridhar P. Gejji
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Biological and related applications of pillar[n]arenes
Chemical Communications, 2017This review article summarizes the advance of pillar[n]arene chemistry in terms of its application in biological and related fields.
CuhaWijay Sathiyajith +5 more
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Synthesis and inclusion properties of pillar[n]arenes
Journal of Inclusion Phenomena and Macrocyclic Chemistry, 2012A detailed study of the reaction conditions revealed that a quantitative cyclocondensation of 1,4-dialkoxy-2,5-bis(alkoxymethyl)-benzenes to pillar[n]arenes can be achieved by catalysis of p-toluenesulfonic acid in CH2Cl2. Major product of this new reaction is in each case a cyclopentamer (n = 5), but small amounts of the pillar[n]arenes with n = 6, 7 ...
Yuhui Kou +6 more
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ChemInform Abstract: Functionalizing Pillar[n]arenes
ChemInform, 2014AbstractReview: 52 refs.
Nathan L. Strutt +3 more
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Pillar[n]arene-based polymeric systems for biomedical applications
Coordination Chemistry Reviews, 2023National Research Foundation (NRF)
Le Zhou +4 more
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