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LCST Behavior of Symmetrical PNiPAm-b-PEtOx-b-PNiPAm Triblock Copolymers
Macromolecules, 2016Poly(N-isopropylacrylamide) (PNiPAm) and poly(2-ethyl-2-oxazoline) (PEtOx) represent two polymer types that are well-known for their lower critical solution temperature (LCST) behavior in aqueous media. To synthesize triblock copolymers containing both polymers, a crossover of two different polymerization methods was applied using a bifunctional ...
Dirauf, Michael +6 more
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Preparation and Properties of Cyclodextrin/PNIPAm Microgels
Macromolecular Bioscience, 2009AbstractA two‐stage precipitation polymerization in aqueous solution was used to prepare β‐cyclodextrin/poly(N‐isopropylacrylamide) (β‐CD/PNIPAm) core–shell microgels. At the first stage, core microgels with CD moieties were synthesized by precipitation copolymerization of N‐isopropylacrylamide (NIPAm) with a monovinyl β‐CD monomer. At the second stage,
Yu-Yang, Liu +4 more
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Langmuir, 2004
The adsorption of a rhodamine X labeled oligonucleotide composed of 25-mers of thymine (dT(25)-ROX) onto the thermosensitive shell of PMMA/PNIPAM core-shell latex particles was studied at 22 and 40 degrees C, below and above the T(VPT) (volume phase transition temperature) of the PNIPAM shell, respectively.
T J V, Prazeres +4 more
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The adsorption of a rhodamine X labeled oligonucleotide composed of 25-mers of thymine (dT(25)-ROX) onto the thermosensitive shell of PMMA/PNIPAM core-shell latex particles was studied at 22 and 40 degrees C, below and above the T(VPT) (volume phase transition temperature) of the PNIPAM shell, respectively.
T J V, Prazeres +4 more
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Multi-responsive PNIPAM–PEGDA hydrogel composite
Soft Matter, 2021PNIPAM–PEGDA hydrogels in response to temperature, solvent and magnetic fields.
Liqian Wang +4 more
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Physical Chemistry Chemical Physics, 2013
The solution behaviors and microstructures of poly(N-isopropylacrylamide)x-poly(ethylene oxide)20-poly(propylene oxide)70-poly(ethylene oxide)20-poly(N-isopropylacrylamide)x (PNIPAmx-PEO20-PPO70-PEO20-PNIPAmx or PNIPAmx-P123-PNIPAmx) pentablock terpolymers with various PNIPAm block lengths in dilute and concentrated aqueous solutions were investigated ...
Yanping, Lu +8 more
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The solution behaviors and microstructures of poly(N-isopropylacrylamide)x-poly(ethylene oxide)20-poly(propylene oxide)70-poly(ethylene oxide)20-poly(N-isopropylacrylamide)x (PNIPAmx-PEO20-PPO70-PEO20-PNIPAmx or PNIPAmx-P123-PNIPAmx) pentablock terpolymers with various PNIPAm block lengths in dilute and concentrated aqueous solutions were investigated ...
Yanping, Lu +8 more
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Colloidal Phase Separation of Concentrated PNIPAm Solutions
Langmuir, 2007In the concentration range of 1-6 wt %, solutions of a thermosensitive polymer (poly-N-isopropylacrylamide (PNIPAm), Mw = 1.4 x 10(5) g.mol(-1)) are shown to phase separate in the form of dense stable colloids of nearly pure polymer. Diffuse wave spectroscopy and small-angle neutron scattering both provide consistent measurements of the colloidal size ...
Balu, C. +4 more
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Colloid and Polymer Science, 2012
Thermosensitive PNIPAM microcontainers were prepared by using silica particles as template. Silica particles were prepared by the Stober method and surface modified with linear P(NIPAM-co-MPS) chains. PNIPAM shell was then fabricated on the P(NIPAM-co-MPS)-modified silica particles through precipitation polymerization of NIPAM and MBA.
Feng Zhang +4 more
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Thermosensitive PNIPAM microcontainers were prepared by using silica particles as template. Silica particles were prepared by the Stober method and surface modified with linear P(NIPAM-co-MPS) chains. PNIPAM shell was then fabricated on the P(NIPAM-co-MPS)-modified silica particles through precipitation polymerization of NIPAM and MBA.
Feng Zhang +4 more
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Mechanical properties of PNIPAM based hydrogels: A review
Materials Science and Engineering: C, 2017Materials which adjust their properties in response to environmental factors such as temperature, pH and ionic strength are rapidly evolving and known as smart materials. Hydrogels formed by smart polymers have various applications. Among the smart polymers, thermoresponsive polymer poly(N-isopropylacrylamide)(PNIPAM) is very important because of its ...
Muhammad Abdul, Haq +2 more
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PNIPAM microgels in external fields
2018Thermoresponsible Mikrogele aus Poly(N-isopropylacrylamid) (PNIPAM) quellen in Wasser, aber schrumpfen oberhalb ihrer Volumenphasenübergangstemperatur (VPTT). Außerdem schrumpfen sie in Mischungen aus Wasser und Ethanol, obwohl beide einzeln gute Lösungsmittel sind. Dies wird als cononsolvency bezeichnet.
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PNIPAm-PEO-PPO-PEO-PNIPAm Pentablock Terpolymer: Synthesis and Chain Behavior in Aqueous Solution
Macromolecules, 2010The double thermosensitive and narrow dispersed PNIPAm110-PEO100-PPO65-PEO100-PNIPAm110 pentablock terpolymer was synthesized by the typical atomic transfer radical polymerization (ATRP) method with N-isopropylacrylamide (NIPAm) as the monomer and modified poly(ethylene oxide)100−poly(propylene oxide)65−poly(ethylene oxide)100 (PEO100-PPO65-PEO100 ...
Aixiong Mei +6 more
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