Results 251 to 260 of about 15,235,426 (349)

Oxidative Rearrangements of the Alkaloid Intermediate Geissoschizine

open access: yesAngewandte Chemie, EarlyView.
19E‐geissoschizine is a key precursor in the biosynthesis of monoterpene indole alkaloids such as strychnine, ibogaine, and vinblastine. Using enzymatic assays and gene silencing, three CYPs were identified from C. roseus that oxidize this compound to four alkaloid scaffolds: strychnos, sarpagan, akuammiline, and mavacurane. Mutational analysis reveals
Mohamed O. Kamileen   +6 more
wiley   +2 more sources

Coupling of CuO@NiBiOx Catalyzed Glycerol Oxidation to Carbon Dioxide Reduction Reaction for Enhanced Energy Efficiency

open access: yesAngewandte Chemie, EarlyView.
A CuOx@NiBiOx core‐shell‐like catalyst is synthesized. Thanks to the Bi presence, the electronic structure of Ni is tuned, leading to better catalytic performance for glycerol oxidation compared to both CuOx and CuOx@NiOx catalysts. Additionally, coupling glycerol oxidation with CO2 reduction significantly reduces the operational voltage and the ...
Thi‐Hong‐Hanh Le   +13 more
wiley   +2 more sources

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