Results 171 to 180 of about 60,059 (301)

Molecular Bottom‐Up Design of Single‐Site Copper‐Palladium Catalysts for Selective Glycerol Electro‐Oxidation

open access: yesAdvanced Energy Materials, EarlyView.
A bimetallic Cu‐Pd single‐site catalyst for the selective and efficient electrooxidation of glycerol to formate and C3‐products (lactate, glycolate, glycerate) is reported. Experimental and theoretical studies shed light on the catalyst function and reveal that Pd sites facilitate the adsorption of hydroxyl (C‐OH) species which prevents C‐C bond ...
Soressa Abera Chala   +19 more
wiley   +1 more source

Poison Control Center Liability

open access: yesAmerican Journal of Pharmaceutical Education, 1984
openaire   +2 more sources

Hierarchical Fluorinated Polymer Separator Design Mitigating Bilateral Ionic Crosstalk in Aqueous Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Aqueous zinc‐ion batteries suffer from rapid decay under practical conditions due to bilateral Zn2+/Mn2+ ionic crosstalk, a system‐level failure mechanism. We develop a hierarchical fluorinated polymer separator that regulates ion fluxes and stabilizes both electrodes simultaneously. This strategy enables extended cycle life while maintaining capacity,
Mei Han   +8 more
wiley   +1 more source

From Heat to Electrons: Bridging Heterogeneous Liquid‐Phase Thermal and Electrocatalytic Oxidation of Ethylene Glycol over Co3O4

open access: yesAngewandte Chemie, EarlyView.
The aerobic liquid‐phase thermal oxidation of ethylene glycol and its electrocatalytic oxidation resulted in the same product distribution using mesostructured Co3O4. Ab initio molecular dynamics simulations reveal analogous surface intermediates requiring Co3+ centers and OH− species with O2 or the anodic potential regenerating the reduced active ...
Catalina Leiva‐Leroy   +9 more
wiley   +2 more sources

Advancing Direct Alcohol Fuel Cells: Innovations in Composite‐Based Electrocatalysts and Polymer Support Materials for Enhanced Efficiency

open access: yesAdvanced Energy and Sustainability Research, EarlyView.
This graphical abstract emphasizes the working principle and the various essential factors of the direct methanol fuel cell (DMFCs). Additionally, various parameters, such as the nanoparticle's size and shape, the nature of the electrolyte, the type of support materials, and their fabrication process, also play essential roles in the functioning of the
Kirti Mishra   +3 more
wiley   +1 more source

Bench‐Stable Boryl Thianthrenium Dication Enables Aziridinyl Boronate Synthesis via Metal‐Free Late‐Stage Aziridination with Diverse Nitrogen Nucleophiles

open access: yesAngewandte Chemie, EarlyView.
A bench‐stable boryl thianthrenium dication is synthesized via thianthrenation of vinyl MIDA boronate. This novel dication enables metal‐free, chemo‐, and diastereoselective late‐stage aziridination with diverse nitrogen nucleophiles. The strategic significance is further showcased by one‐pot electrochemical and asymmetric protocols and versatile ...
Veerabhadra R. Vulupala   +7 more
wiley   +2 more sources

Strategies for Paired Electrolysis with Enhanced Efficiency

open access: yesAdvanced Energy and Sustainability Research, EarlyView.
This review summarizes the fundamentals, challenges, and strategies for paired electrolysis, with examples in the chlor‐alkali, hydrogen production, CO2 reduction, and ammonia synthesis industries. Future directions include the development of advanced membranes, computational studies, process integration, scale‐up, and techno‐economic analysis.
Yuanyuan Yao   +6 more
wiley   +1 more source

Transitioning of the Chemical Industry Toward a Net‐Zero Carbon Dioxide Emission Path

open access: yesAngewandte Chemie, EarlyView.
One way to reduce the greenhouse gas footprint of the chemical industry to almost zero would be the production of the platform molecules C1‐compounds, olefins, aromatics, and ammonia by non‐fossil pathways. The rest of the chemical production chains could be essentially left unchanged, provided the process energy input is renewable.
Ferdi Schüth, Stephan A. Schunk
wiley   +2 more sources

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