Results 231 to 240 of about 60,059 (301)

Probing the Effect of Spectator Anions on Chloride Adsorption for Selective Oxygen Evolution Reaction over Ni Catalysts

open access: yesChemElectroChem, EarlyView.
After the oxidation of Ni(OH)2, chloride ions adsorb on the NiOOH surface, leading to OCl− formation through the chlorine oxidation reaction and partial Ni dissolution. In contrast, the presence of a spectator anion layer on NiOOH inhibits chloride adsorption and improves the selectivity of the oxygen evolution reaction.
Kahyun Ham   +4 more
wiley   +1 more source

Metal‐Free Covalent Organic Frameworks for Photocatalytic CO2 Reduction

open access: yesChemistryEurope, EarlyView.
This review presents an environmentally sustainable strategy to address the critical issue of escalating atmospheric CO2 levels. It explores the application of metal‐free covalent organic frameworks in a photocatalytic approach, offering a green and efficient strategy for carbon dioxide reduction and contributing to climate change mitigation.
Supriti Dutta   +3 more
wiley   +1 more source

Recent Advances in Tailoring Active Site Microenvironments of Fe–N–C Catalysts for Oxygen Reduction

open access: yesChemistryEurope, EarlyView.
This review summarizes the main factors affecting Fe–N–C catalysts for ORR: activity depends on active site structure, electronic configuration, and porosity, while stability is limited by metal leaching, carbon degradation, and inactive phase formation.
Mudassar Maqsood   +6 more
wiley   +1 more source

Oxide Interface of Gallium‐Based Liquid Metals: Beneficial Bridge or Hidden Risk?

open access: yesChemistryEurope, EarlyView.
Discussion on oxide interfaces in gallium‐based liquid metals have concentrated on their properties, behaviors, and related applications. However, the molecular mechanisms underlying effects, as well as the differences between the presence and absence of the oxide layer, have been less thoroughly discussed.
Yi Fan, Shuai Wang, Xu Hou
wiley   +1 more source

Rubrolides A, D, P, T, U: Total Syntheses and Antibacterial Evaluation of Highly Brominated Marine Natural Products

open access: yesChemistryEurope, EarlyView.
Following the Danube Flow. The first total syntheses of highly brominated rubrolides T, U, and U‐analog, together with the efficient and divergent syntheses of rubrolides A, D, and P. The dibrominated key intermediate, obtained via a Suzuki‐Miyaura cross‐coupling reaction, is the centerpiece of the synthesis.
Jasmin Janneschütz   +7 more
wiley   +1 more source

Defect‐Anchored Iridium Single Atoms on Palladium Metallenes for Synergistically Enhanced Ethanol Oxidation Reaction

open access: yesChemistryEurope, EarlyView.
This work presents a defect‐site activation strategy, in which anchoring Ir single atoms onto the highly strained defects of Pd metallene generates synergistic PdIr sites, leading to a dramatic enhancement in the ethanol oxidation reaction. The development of highly efficient electrocatalysts for the ethanol oxidation reaction (EOR) is critical to the
Wenbo Li   +6 more
wiley   +1 more source

Precision Catalysis in Dehydrogenation of Liquid Organic Hydrogen Carriers: Molecular Structure‐Geometry‐Electronic Interplay for Enhanced Hydrogen Evolution

open access: yesCarbon Energy, EarlyView.
Atomic‐scale design principles for LOHC dehydrogenation: Tailoring geometric and electronic effects in metal catalysts to bridge the molecular structure of LOHC and dehydrogenation performance. ABSTRACT The advancement of hydrogen‐based energy systems necessitates innovative solutions for safe, efficient hydrogen storage and transportation.
Yongxiao Tuo   +8 more
wiley   +1 more source

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