Results 161 to 170 of about 1,669,914 (242)

Interfacial Mn‐Carbon Nitride Synergy Enables Selective Photocatalytic C─H Chlorination via Single‐Atom Catalysis

open access: yesAngewandte Chemie International Edition, EarlyView.
A manganese single‐atom photocatalyst on functionalised carbon nitride enables selective visible‐light‐driven C(sp2)─H chlorination. DFT‐supported mechanistic studies indicate that photoinduced charge separation activates NCS, while isolated Mn sites stabilize Mn─Cl intermediates at the catalyst interface.
Jaro Vanderghinste   +16 more
wiley   +1 more source

Relationship Between Feed Olfactory Exploration and Consumption in Horses. [PDF]

open access: yesAnimals (Basel)
Wnuk E   +5 more
europepmc   +1 more source

The Manifestation of the Electrochemical Potential Gradient in the Kinetic Landscapes of Interfacial Electrochemistry

open access: yesAngewandte Chemie International Edition, EarlyView.
The overpotential constitutes an electrochemical potential difference at the solid–liquid interface, which can manifest itself in different ways. In general, it can not only drive the reaction along the reaction coordinate, but also modulate chemical potentials in the extended environment that shape activation barriers, without necessarily being a ...
Sebastian Z. Oener   +10 more
wiley   +1 more source

Unraveling the Importance of Surface Hydrogen Diffusion in Photocatalysis by Isotope Probing

open access: yesAngewandte Chemie International Edition, EarlyView.
Surface hydrogen diffusion on titanium dioxide is identified as a crucial step in photocatalytic hydrogen evolution. Demonstrated by deuterium substitution in methanol, restricted diffusion to the co‐catalyst leads to hindered formation of molecular hydrogen and a high KIE.
Philip Petzoldt   +5 more
wiley   +1 more source

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