Results 11 to 20 of about 2,685 (250)

Synthesis and Characterization of NaCd0.92Sn1.08, Na(Cd0.28Sn0.72)2 and Na2CdSn5 with Three-Dimensional Cd-Sn Frameworks

open access: yesInorganics, 2021
The crystal structures of three new ternary compounds, NaCd0.92Sn1.08 (I), Na(Cd0.28Sn0.72)2 (II), and Na2CdSn5 (III) synthesized in a sodium-cadmium-tin system were determined by single-crystal X-ray analysis to be the following: (I) LiGeZn-type ...
Yuki Asamiya   +2 more
doaj   +1 more source

Revealing the Bonding Nature in an ALnZnTe3-Type Alkaline-Metal (A) Lanthanide (Ln) Zinc Telluride by Means of Experimental and Quantum-Chemical Techniques

open access: yesCrystals, 2020
Tellurides have attracted an enormous interest in the quest for materials addressing future challenges, because many of them are at the cutting edge of basic research and technologies due to their remarkable chemical and physical properties.
Katharina Eickmeier, Simon Steinberg
doaj   +1 more source

Revisiting the Zintl‒Klemm Concept for ALn2Ag3Te5-Type Alkaline-Metal (A) Lanthanide (Ln) Silver Tellurides

open access: yesCrystals, 2020
Understanding the bonding nature of solids is decisive, as knowledge of the bonding situation for any given material provides valuable information about its structural preferences and physical properties.
Katharina Eickmeier   +4 more
doaj   +1 more source

Caloric effects around phase transitions in magnetic materials described by ab initio theory : the electronic glue and fluctuating local moments [PDF]

open access: yes, 2020
We describe magneto-, baro-, and elastocaloric effects (MCEs, BCEs, and eCEs) in materials, which possess both discontinuous (first-order) and continuous (second-order) magnetic phase transitions.
Mendive-Tapia, Eduardo   +1 more
core   +2 more sources

Revealing the Nature of Chemical Bonding in an ALn2Ag3Te5-Type Alkaline-Metal (A) Lanthanide (Ln) Silver Telluride

open access: yesInorganics, 2019
Although the electronic structures of several tellurides have been recognized by applying the Zintl-Klemm concept, there are also tellurides whose electronic structures cannot be understood by applications of the aforementioned idea.
Kai C. Göbgen   +4 more
doaj   +1 more source

H-T Phase Diagram of Rare-Earth -- Transition Metal Alloy in the Vicinity of the Compensation Point [PDF]

open access: yes, 2019
Anomalous hysteresis loops of ferrimagnetic amorphous alloys in high magnetic field and in the vicinity of the compensation temperature have so far been explained by sample inhomogeneities.
Becker, J.   +4 more
core   +2 more sources

High-resolution resonant inelastic soft X-ray scattering as a probe of the crystal electrical field in lanthanides demonstrated for the case of CeRh2Si2 [PDF]

open access: yes, 2018
The magnetic properties of rare earth compounds are usually well captured by assuming a fully localized f shell and only considering the Hund's rule ground state multiplet split by a crystal electrical field (CEF).
Amorese, A.   +8 more
core   +2 more sources

Rhombohedral Distortion of the Cubic MgCu2-Type Structure in Ca2Pt3Ga and Ca2Pd3Ga

open access: yesCrystals, 2018
Two new fully ordered ternary Laves phase compounds, Ca2Pt3Ga and Ca2Pd3Ga, have been synthesized and characterized by powder and single-crystal X-ray diffraction along with electronic structure calculations.
Asa Toombs, Gordon J. Miller
doaj   +1 more source

Single crystal growth and characterization of the large-unit-cell compound Cu13Ba [PDF]

open access: yes, 2013
Single crystals of Cu$_{13}$Ba were successfully grown out of Ba-Cu self flux. Temperature dependent magnetization, $M(T)$, electrical resistivity, $\rho(T)$, and specific heat, $C_p(T)$, data are reported.
Bud’ko, Sergey   +3 more
core   +3 more sources

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