Polarization electrochemistry - Open Access .click

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DFT Modeling of Stark-Tuning Effect: CO on Polarized Pd(100) as a Probe for Double-Layer Electrostatic Effects in Electrochemistry

2005
The lifetime of chemisorbed radical anions produced in the electroreduction of vinylic molecules is thought to play a decisive part in the mechanism accounting for the production of grafted films in electropolymerization reactions. With the ultimate purpose of evaluating these lifetimes, we propose a one-dimensional model taking into account the ...
Xavier Crispin +3 more
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Polarized Bimetallic Site Synergy in Ionic Structures of Cu(II), Fe(III), and Mn(III) Porphyrins: Electrochemistry and Catalytic Hydrogenation of Nitroaromatics

Inorganic Chemistry
Binuclear catalytic sites attained in a controlled way with complementary and cooperative metal ion centers are highly relevant in the development of new or enhanced catalytic processes. Herein, binuclear sites carrying Fe(III), Cu(II), or Mn(III) metal ions with a polarized structure have been prepared using the ionic self-assembly of oppositely ...
Gabriela A. Corrêa +3 more
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Accounting for Metallicity, Polarization of the Electrolyte, and Redox reactions in computational Electrochemistry