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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Marina Privman, Tadeusz Hepel
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We report the synthesis, crystal structure, and magnetic, electrochemical, and carrier-transport properties of vanadyl tetrakis(thiadiazole)porphyrazine (abbreviated as VOTTDPz) with S = ½. X-ray crystal analysis reveals two polymorphs, the α and β forms; the former consists of a 1D regular π stacking, while the latter forms a 2D π network.
Yasuhito Miyoshi+10 more
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Electrochemistry of lithium trivanadate (LiV3O8, LVO) has been extensively studied due to its large capacity and high rate capability. The material undergoes both insertion/extraction and phase transform reactions during discharge and charge in a Li-ion battery. However, the rate limiting factors of the material are unclear over the cycling window of
Yiman Zhang+5 more
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Extra capacity beyond electrochemistry: electrons storage by spin-polarization
Huicong Yang, Feng Li
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Dependence of Quinone Electrochemistry on Solvent Polarity and pH
Journal of The Electrochemical Society, 2022We studied the polarographic reduction of quinones in aqueous/organic mixtures with dielectric constants (ε) from 78.4 down to 47. Added organic co-solvents were either protic or aprotic. The increase in polarographic half-wave potential,E1/2, with decliningεwas successfully fit to the Born equation down toε≈ 55.
Todd P. Silverstein, Jason R. Rosé
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Interfacial Electrochemistry of ZnO: An Influence of the Surface Polarity?
ECS Meeting Abstracts, 2009Abstract not Available.
Anne-Laure Joudrier+6 more
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Alleviating the common confusion caused by polarity in electrochemistry
Journal of Chemical Education, 1989The issue of polarity encountered in electrochemistry and relevant to a variety of electrochemical concepts often confuses students and is an unnecessary deterrent to the study of electrochemistry.
P. J. Moran, E. Gileadi
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Synthesis, structure, electrochemistry, and photophysics of 2,5-dibenzylidenecyclopentanones containing in benzene rings substituents different in polarity [PDF]
A series of cross-conjugated dienones was synthesized to study the dependence of physicochemical characteristics on the nature of substituents in the aromatic groups of symmetric cyclopentanone dibenzylidene derivatives. The structure of compounds was established by electronic, IR, and NMR spectroscopy and X-ray diffraction study.
V. N. Nuriev+12 more
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The Electrochemistry of Nickel
Journal of The Electrochemical Society, 1963Abstract : The anodic dissolution of Ni was studied in acidified chloride, sulfate, and perchlorate solutions under a variety of non-passivating conditions. The Tafel slopes at 45 deg C are approximately 0.085, 0.115, 0.12, respectively. The lower value of the Tafel slope in chloride solutions is attributed to specific adsorption.
E. Yeager+3 more
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Angewandte Chemie, 2000
The noncoordinating anion [B(C(6)F(5))(4)](-) solubilizes cations and polycations, allowing the generation and study of such systems in low-dielectric media. Thus, when [NBu(4)][B(C(6)F(5))(4)] is used as a supporting electrolyte, cyclic voltammetry is possible in aliphatic ethers and other solvents of very low polarity.
William E. Geiger, Robert J. LeSuer
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The noncoordinating anion [B(C(6)F(5))(4)](-) solubilizes cations and polycations, allowing the generation and study of such systems in low-dielectric media. Thus, when [NBu(4)][B(C(6)F(5))(4)] is used as a supporting electrolyte, cyclic voltammetry is possible in aliphatic ethers and other solvents of very low polarity.
William E. Geiger, Robert J. LeSuer
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