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Structural and Optical Properties of Inherently Chiral Polythiophenes: A Combined CD-Electrochemistry, Circularly Polarized Luminescence, and TD-DFT Investigation

The Journal of Physical Chemistry C, 2014
Circular dichroism (CD) and ultraviolet absorption (UV) spectra of films obtained by electrochemical polymerization of inherently chiral 2,2′-bis(2,2′-bithiophene-5-yl)-3,3′-bithianaphthene (T4-BT2...
LONGHI, Giovanna   +7 more
openaire   +2 more sources

Ultrasonic Waves and Electrochemistry. V. The Frequency Characteristics the Electrokinetic and the AC Polarized Gas Electrode Effects

The Journal of the Acoustical Society of America, 1955
The frequency characteristics of the acousto-electrokinetic effect and the ac polarized gas electrode effect have been determined with pulse-modulated ultrasonic waves in the range 200 to 1000 kc/sec as a function of solution and electrode parameters.
Frank Hovorka   +2 more
openaire   +2 more sources

Ultrasonic Waves and Electrochemistry. IV. The Production of Alternating Components in the Potential of a Polarized Hydrogen Electrode with Ultrasonic Waves

The Journal of the Acoustical Society of America, 1953
If sound waves interact with an electrode upon which a gas is being liberated by electrolysis, an alternating potential of the same frequency is developed on the electrode relative to the bulk of the surrounding solution. The effect has been studied in the case of a polarized hydrogen electrode with pulse-modulated ultrasonic waves at a frequency of ...
John Bugosh   +3 more
openaire   +2 more sources

The electrochemistry of the tin oxide semiconductor—I. the establishment of mechanisms at polarized n-type tin oxide

Electrochimica Acta, 1972
Abstract The mechanisms of electrode potential re-establishment of the n-type unstoichiometrical tin oxide semiconductor electrode after cathodic and anodic polarization was investigated. The tin oxide semiconductor was polarized cathodically and anodically without evolution of hydrogen or oxygen and the potential/time curves at open circuit were ...
openaire   +2 more sources

Electrochemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane (L) at the polarized water/1,2-dichloroethane interface: Evaluation of the complexation properties towards transition and post-transition metal ions

Journal of Electroanalytical Chemistry, 2006
Abstract The coordination chemistry of 2,8-dithia[9],(2,9)-1,10-phenanthrolinophane ( L ) towards transition and post -transition metal ions such as Cu(II), Cu(I), Cd(II), Co(II), Ni(II), Pb(II) and Zn(II) was studied at the polarized water/1,2-dichloroethane interface by cyclic voltammetry.
E. S. FERREIRA   +4 more
openaire   +3 more sources

Electrochemistry in Non-Polar Media Enabled By New Lipophilic Salts

ECS Meeting Abstracts, 2018
There is little known about electrochemical behavior in non-polar media due to lack of compatible, lipophilic salts. [1] Herein, this difficult challenge has been overcome by following a strategy based on designing and synthesizing a novel family of organic salts with highly-delocalized cations and anions. The salts show good miscibility in heptane,
openaire   +1 more source

DFT Modeling of Stark-Tuning Effect: CO on Polarized Pd(100) as a Probe for Double-Layer Electrostatic Effects in Electrochemistry

2005
The lifetime of chemisorbed radical anions produced in the electroreduction of vinylic molecules is thought to play a decisive part in the mechanism accounting for the production of grafted films in electropolymerization reactions. With the ultimate purpose of evaluating these lifetimes, we propose a one-dimensional model taking into account the ...
Xavier Crispin   +3 more
openaire   +2 more sources

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