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AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
Marina Privman, Tadeusz Hepel
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We report the synthesis, crystal structure, and magnetic, electrochemical, and carrier-transport properties of vanadyl tetrakis(thiadiazole)porphyrazine (abbreviated as VOTTDPz) with S = ½. X-ray crystal analysis reveals two polymorphs, the α and β forms; the former consists of a 1D regular π stacking, while the latter forms a 2D π network.
Yasuhito Miyoshi +10 more
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Abstract Corrosion of steel in portland cement concrete has been found to be very damaging and costly to many countries in the world. It is possible to control this corrosion damage in several ways and one of these is the use of inhibitors.
Carl E. Locke +1 more
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AbstractTransition metal oxide electrocatalysts (TMOEs) are poised to revive grid‐scale all‐vanadium redox flow batteries (VRFBs) due to their low‐cost and unique electronic properties, while often inescapably harboring surface vacancies. The role of local vacancy‐induced physicochemical properties on vanadium‐redox electrochemistry (VRE), encompassing
Xiangyang Zhang +9 more
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Abstract Surface concentration polarization induces fouling processes accompanied by changes in the resistance of a semipermeable membrane, but the connection between these two phenomena has not yet been evaluated. Here, we propose to connect them by introducing the concept of pH equivalent (pHeq), which is used to describe the electrical properties ...
Lingling Li +4 more
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Electrochemistry of lithium trivanadate (LiV3O8, LVO) has been extensively studied due to its large capacity and high rate capability. The material undergoes both insertion/extraction and phase transform reactions during discharge and charge in a Li-ion battery. However, the rate limiting factors of the material are unclear over the cycling window of
Yiman Zhang +5 more
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Extra capacity beyond electrochemistry: electrons storage by spin-polarization
Huicong Yang, Feng Li
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Dependence of Quinone Electrochemistry on Solvent Polarity and pH
Journal of The Electrochemical Society, 2022We studied the polarographic reduction of quinones in aqueous/organic mixtures with dielectric constants ( ε ) from 78.4 down to 47. Added organic co-solvents were either protic or aprotic. The increase in polarographic half-wave potential, E 1/2
Todd P. Silverstein, Jason R. Rosé
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Alleviating the common confusion caused by polarity in electrochemistry
Journal of Chemical Education, 1989The issue of polarity encountered in electrochemistry and relevant to a variety of electrochemical concepts often confuses students and is an unnecessary deterrent to the study of electrochemistry.
P. J. Moran, E. Gileadi
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