Amidinium salts: Towards enabling electrochemistry in non-polar media from alkanes to ionic liquids
Abstract There is little known about electrochemical behavior in non-polar media due to lack of compatible, hydrophobic salts. In this work, this difficult challenge has been overcome by following a strategy based on designing and synthesizing a novel family of organic salts with highly-delocalized cations and anions.
Yaser Abu-Lebdeh+3 more
openaire +3 more sources
Triboelectric Junction: A Model for Dynamic Metal-Semiconductor Contacts [PDF]
Static metal-semiconductor contacts are classified into Ohmic contacts and Schottky contacts. As for dynamic metal-semiconductor contacts, the in-depth mechanism remains to be studied. We here define a "triboelectric junction" model for analyzing dynamic metal-semiconductor contacts, where a space charge region induced by the triboelectric effect ...
arxiv
Electrochemistry and Optical Microscopy [PDF]
Electrochemistry exploits local current heterogeneities at various scales ranging from the micrometer to the nanometer. The last decade has witnessed unprecedented progress in the development of a wide range of electroanalytical techniques allowing to reveal and quantify such heterogeneity through multiscale and multifonctionnal operando probing of ...
arxiv +1 more source
Studies on Pitting Corrosion of Al-Cu-Li Alloys Part III: Passivation Kinetics of AA2098-T851 Based on the Point Defect Model. [PDF]
In this paper, the passivation kinetics of AA2098-T851 was investigated by a fundamental theoretical interpretation of experimental results based on the mixed potential model (MPM).
Ghanbari, Elmira+3 more
core +2 more sources
Dynamic polarization of graphene by moving external charges: random phase approximation [PDF]
We evaluate the stopping and image forces on a charged particle moving parallel to a doped sheet of graphene by using the dielectric response formalism for graphene's $\pi$-electron bands in the random phase approximation (RPA). The forces are presented as functions of the particle speed and the particle distance for a broad range of charge-carrier ...
arxiv +1 more source
Dynamics of electrocrystallization of dendritic zinc deposits in galvanostatic and potentiostatic modes [PDF]
In the work the dynamics of growth of zinc dendritic deposits in the galvanostatic and potentiostatic modes from an electrolyte containing 0.3 mol/L of ZnO, and 4 mol/L of NaOH has been studied. It has been shown that in galvanostatic conditions decrease
Farlenkov, А. S.+3 more
core +1 more source
Molecular recognition of polar neutral molecules by metallomacrocycles: synthesis, proton NMR spectroscopy, x-ray structure, electrochemistry, and ab initio calculations [PDF]
AbstractChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
David N. Reinhoudt+6 more
openaire +3 more sources
Influence of interface dipole layers on the performance of graphene field effect transistors [PDF]
The linear band dispersion of graphene's bands near the Fermi level gives rise to its unique electronic properties, such as a giant carrier mobility, and this has triggered extensive research in applications, such as graphene field-effect transistors (GFETs).
arxiv +1 more source
A new composite electrochemistry-dual circuit polarization model (E-DCP) is proposed by combining the advantages of various electrochemical empirical models in this paper.
Haotian Shi+5 more
semanticscholar +1 more source
Laser surface texturing significantly improves the corrosion resistance and mechanical strength of 3D‐printed iron polylactic acid (Ir‐PLA) for marine applications. Optimal laser parameters reduce corrosion by 80% and enhance tensile strength by 25% and ductility by 15%.
Mohammad Rezayat+6 more
wiley +1 more source