Results 61 to 70 of about 83,818 (278)

Mediation of Oxidation and Spin States of Fe/P‐CoO2 Core–Shell Structures Catalysts for Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
Fe‐cationic and P‐anionic coordination, as fabricated in Co0.75Fe0.25P/MWCNTs, effectively optimizes the adsorption of OER intermediates (OH*, O*), promoting direct O*─O* coupling and avoiding the formation of unstable OOH* intermediate. This process is accompanied by an asynchronous transfer of electrons and protons, resulting in the formation of a ...
Hong Lv   +5 more
wiley   +1 more source

Porous Zinc Anode Design for Zn-air Chemistry

open access: yesFrontiers in Chemistry, 2019
Zinc-air battery has drawn increasing attention from the whole world owing to its large energy capacity, stable working voltage, environmentally friendship, and low price.
Peiyuan Liu   +10 more
doaj   +1 more source

Recent Advances in Single‐Atom Catalyst for Solar Energy Conversion: A Comprehensive Review and Future Outlook

open access: yesAdvanced Functional Materials, EarlyView.
This review highlights the potential of single‐atom catalysts in three key photocatalytic reactions: the hydrogen evolution reaction (HER), nitrogen reduction reaction for ammonia synthesis, and carbon dioxide reduction reaction (CO2RR) for chemical fuels.
Saad Mehmood   +5 more
wiley   +1 more source

Comparative Assessment of Nonlocal Continuum Solvent Models Exhibiting Overscreening

open access: yesComputational and Mathematical Biophysics, 2017
Nonlocal continua have been proposed to offer a more realistic model for the electrostatic response of solutions such as the electrolyte solvents prominent in biology and electrochemistry. In this work, we review three nonlocal models based on the Landau-
Ren Baihua, Bardhan Jaydeep P.
doaj   +1 more source

Electrode Polarization in Glassy Electrolytes: Large Interfacial Capacitance Values and Indication for Pseudocapacitive Charge Storage [PDF]

open access: yesarXiv, 2009
We study the electrode polarization behaviour of different Na-Ca-phosphosilicate glasses by measuring the differential capacitance between blocking Pt electrodes. At low applied dc bias voltages, we detect a linear capacitance regime with interfacial capacitance values considerably larger than expected from double layer theories and also considerably ...
arxiv  

Electroplating of Wear‐ and Corrosion‐Resistant CrCoNi Medium‐Entropy Alloys beyond Hard Chromium Coatings

open access: yesAdvanced Functional Materials, EarlyView.
The electroplating of a CrCoNi medium‐entropy alloy is achieved using a mixture of an ionic liquid and an aqueous solution containing metal salts. The CrCoNi medium‐entropy alloy thin film exhibits high wear and corrosion resistance superior to conventional hard chromium coatings. Abstract High‐entropy alloys (HEAs) and medium‐entropy alloys (MEAs) are
Yuki Murakami   +7 more
wiley   +1 more source

Electrochemical tip-enhanced Raman spectroscopy imaging with 8 nm lateral resolution

open access: yesElectrochemistry Communications, 2019
Herein, we report tip-enhanced Raman spectroscopy (TERS) hyperspectral imaging under electrochemical control of a non-Raman-resonant molecular compound. A new setup combining a Scanning Tunneling Microscope (STM) and an optical coupling with high signal ...
Thomas Touzalin   +3 more
doaj  

Anisometric Charge Dependent Swelling of Porous Carbon in an Ionic Liquid [PDF]

open access: yesarXiv, 2013
In situ electrochemical dilatometry was used to study, for the first time, the expansion behavior of a porous carbon electrode in a pure ionic liquid, 1-ethyl-3-methyl-imidazolium-tetrafluoroborate. For a single electrode, an applied potential of -2 V and +2 V against the potential of zero charge resulted in maximum strain of 1.8 % and 0.5 ...
arxiv  

Surface Plasmon Electrochemistry [PDF]

open access: yesarXiv, 2023
Surface plasmon polaritons (SPPs) are optical waves that propagate along a metal surface. They exhibit properties such as sub-wavelength localization and field enhancement which make them attractive for surface sensing, as commonly encountered in surface plasmon biosensors - the most widespread of all optical biosensors. Electrochemistry also occurs on
arxiv  

Transient Current Responses of Organic Electrochemical Transistors: Evaluating Ion Diffusion, Chemical Capacitance, and Series Elements

open access: yesAdvanced Functional Materials, EarlyView.
This work establishes a general theory of the current transient of ionic‐electronic transistors under a step of gate voltage. The dominant effect is a transient charging of the channel by diffusion of ions. The additional influence of electrolyte capacitance and resistance splits the fundamental time constant of diffusion into two different components.
Juan Bisquert, Nir Tessler
wiley   +1 more source

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