Results 151 to 160 of about 30,911 (199)
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Polymer Degradation and Stability, 1992
Abstract The compatibility and biodegradability of a blend of poly(3-hydroxybutyrate) (PHB) and poly(ethylene oxide) (PEO) were studied by analysis of differential scanning calorimetry and enzymatic degradation. The PHB/PEO blend exhibited a single glass-transition temperature (Tg) and the Tg values depended upon the blend composition, which ...
Y.Kumagai, Y.Doi
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Abstract The compatibility and biodegradability of a blend of poly(3-hydroxybutyrate) (PHB) and poly(ethylene oxide) (PEO) were studied by analysis of differential scanning calorimetry and enzymatic degradation. The PHB/PEO blend exhibited a single glass-transition temperature (Tg) and the Tg values depended upon the blend composition, which ...
Y.Kumagai, Y.Doi
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Phase behavior of poly(3-hydroxybutyrate)/poly(3-hydroxybutyrate-co-3-hydroxyvalerate) blends
Fluid Phase Equilibria, 2007Miscibility, molecular interactions and crystallinity of blends of poly(3-hydroxybutyrate) [P(3HB)] with poly(3-hydroxybutyrate-co-3-hydroxyvalerate) [P(3HB-co-3HV)] were studied in this work. P(3HB)/P(3HB-co-3HV)-6%3HV blends were prepared by casting and characterized by differential scanning calorimetry (DSC) and X-ray diffraction (XRD).
Denise Santos Conti +3 more
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Poly-3-hydroxybutyrate production byAzotobacter chroococcum
Folia Microbiologica, 2001Thirty-seven soil isolates and mutants of Azotobacter chroococcum tested for poly-3-hydroxybutyrate (PHB) production using Sudan black B staining method were found to be positive. One mutant showed a higher number of PHB-producing cells and maximum number of granules per cell. Using 2% glucose and 15 mmol/L ammonium acetate, PHB production was found to
J, Parshad +3 more
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Biodegradable Poly(3‐hydroxybutyrate) Nanocomposite
Macromolecular Symposia, 2009AbstractThis work seeks bringing a technological and social contribution by searching blends and composites of poly(3‐hydroxybutyrate) (PHB) and polyethylene widely used in packaging films, and colloidal silica. The mixtures were prepared by extrusion using a single‐screw extruder and were analyzed regarding their thermal and mechanical properties and ...
Eiji Ohashi +6 more
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Photodegradation of poly(3-hydroxybutyrate)
Polymer Degradation and Stability, 2010Abstract The effect of ultraviolet radiation on the properties of poly(3-hydroxybutyrate) (PHB) was studied. The PHB investigated is produced from microbial fermentation using saccharose from sugarcane as the carbon source to the bacteria. The material was exposed to artificial UV-A radiation for 3, 6, 9 and 12 weeks.
Roberta K. Sadi +2 more
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Thermochimica Acta, 2006
Abstract With the objective of developing new biodegradable materials, the miscibility and the crystallinity of blends of poly(3-hydroxybutyrate), P(3HB), and poly(3-hydroxybutyrate-co-3-hydroxyvalerate), P(3HB-co-3HV), have been studied. P(3HB) (300 kg mol−1)/P(3HB-co-3HV)–10% 3HV (340 kg mol−1) blends were prepared by casting in a wide range of ...
D.S. Conti +3 more
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Abstract With the objective of developing new biodegradable materials, the miscibility and the crystallinity of blends of poly(3-hydroxybutyrate), P(3HB), and poly(3-hydroxybutyrate-co-3-hydroxyvalerate), P(3HB-co-3HV), have been studied. P(3HB) (300 kg mol−1)/P(3HB-co-3HV)–10% 3HV (340 kg mol−1) blends were prepared by casting in a wide range of ...
D.S. Conti +3 more
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European Polymer Journal, 2002
Nonisothermal crystallization and melting behavior of poly(3-hydroxybutyrate) (PHB) and maleated PHB were investigated by differential scanning calorimetry using various cooling rates. The results show that the crystallization behavior of maleated PHB from the melt greatly depends on cooling rates and its degree of grafting.
Cheng Chen +5 more
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Nonisothermal crystallization and melting behavior of poly(3-hydroxybutyrate) (PHB) and maleated PHB were investigated by differential scanning calorimetry using various cooling rates. The results show that the crystallization behavior of maleated PHB from the melt greatly depends on cooling rates and its degree of grafting.
Cheng Chen +5 more
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Journal of Applied Polymer Science, 2001
AbstractThermal analyses of poly(3‐hydroxybutyrate) (PHB), poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) [P(HB–HV)], and poly(3‐hydroxybutyrate‐co‐3‐hydroxyhexanoate) [P(HB–HHx)] were made with thermogravimetry and differential scanning calorimetry (DSC).
Ji‐Dong He +3 more
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AbstractThermal analyses of poly(3‐hydroxybutyrate) (PHB), poly(3‐hydroxybutyrate‐co‐3‐hydroxyvalerate) [P(HB–HV)], and poly(3‐hydroxybutyrate‐co‐3‐hydroxyhexanoate) [P(HB–HHx)] were made with thermogravimetry and differential scanning calorimetry (DSC).
Ji‐Dong He +3 more
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Carboxylate-Induced Degradation of Poly(3-hydroxybutyrate)s
Biomacromolecules, 2007This communication shows that thermal degradation of poly(3-hydroxybutyrate)s (PHBs) is induced by carboxylate groups via a newly proposed E1cB mechanism. In PHBs with end groups in the form of carboxylic acid salts with Na+, K+, and Bu4N+ counterions, the proposed mechanism explains the dependence of thermal stability on the size of the counterion ...
M. Kawalec +6 more
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Journal of Applied Polymer Science, 2002
AbstractThe thermal decomposition mechanism of maleated poly(3‐hydroxybutyrate) (PHB) was investigated by FTIR and 1H NMR. The results of experiments showed that the random chain scission of maleated PHB obeyed the six‐membered ring ester decomposition process.
Cheng Chen +5 more
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AbstractThe thermal decomposition mechanism of maleated poly(3‐hydroxybutyrate) (PHB) was investigated by FTIR and 1H NMR. The results of experiments showed that the random chain scission of maleated PHB obeyed the six‐membered ring ester decomposition process.
Cheng Chen +5 more
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