Results 1 to 10 of about 1,007 (177)
Synergistic Hydrogen-Bonding and Covalent Crosslinking in Polybenzimidazole Membranes for Wide-Temperature Anhydrous Fuel Cells. [PDF]
Adv Sci (Weinh)A dual‐network architecture combining a thermally reinforced hydrogen‐bonding matrix with an amine‐anhydride covalent framework was constructed in Tröger's Base (TB)‐functionalized polybenzimidazoles. This design yielded the TBAm‐PBI‐TB membrane with high acid uptake (469.5%), anhydrous conductivity (264.7 mS cm−1), and robust stability.
Dai J +6 more
europepmc +3 more sources
Ordered Ionic‐Liquid Channels Enable Fast Anhydrous Proton Conduction at up to 240°C for Fuel Cells
Angewandte Chemie, EarlyView.Infiltration of ionic liquids into a composite scaffold comprised of graphene and boron nitride nanosheets functionalised with positively charged polyethyleneimine produces robust proton conducting membranes for the intermediate temperature electrochemical devices.
Mazin Al‐Alawi +8 more
wiley +2 more sources
High Free‐Volume Imidazole‐Based Ionomers for High‐Temperature Proton Exchange Membrane Fuel Cells
Advanced Science, EarlyView.High free‐volume imidazole‐based ionomers (PF4IM‐72) enable enhanced phosphoric acid uptake and efficient proton transport, delivering peak power densities of 0.645 W cm−2 at 160 °C and 0.838 W cm−2 at 200 °C in HT‐PEMFCs. This work highlights a promising platform for next‐generation ionomers with improved high‐temperature performance and stability ...
Ge Chao +7 more
wiley +1 more source
Advanced Energy Materials, EarlyView.Embedding imidazolium‐biphosphate ion pairs directly into the polybenzimidazole main chain simultaneously stabilizes phosphoric acid and preserves continuous proton transport pathways. Strong ion‐pair and hydrogen‐bond interactions suppress acid leaching while maintaining high conductivity, enabling stable and durable high‐temperature fuel cell ...
Huina Lin, Brian C. Benicewicz
wiley +1 more source
Citation: 'polybenzimidazoles' in the IUPAC Compendium of Chemical Terminology, 5th ed.; International Union of Pure and Applied Chemistry; 2025. Online version 5.0.0, 2025. 10.1351/goldbook.08888 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms ...
Munmaya Mishra, Biao Duan
openaire +2 more sources
High‐performance conducting polybenzimidazoles nanohybrids
Polymer Composites, 2017 The use of ionic liquids (IL) and nanoparticles in polymeric membranes is known to increase the electrochemical performance for heavy metal ions must be eliminated from water resources. In this study at first, NiFe2O4 and Fe3O4 nanoparticles were obtained using cationic surfactants cetyltrimethylammonium bromide (CTAB) at 120°C in autoclave.
I. Ozaytekin +5 more
openaire +3 more sources
High‐Energy‐Density Redox Flow Batteries: Mechanisms, Design Strategies, and Recent Progress
Chemistry – A European Journal, EarlyView.ABSTRACT The inherent intermittency of energy sources such as solar and wind power hinders the transition to renewable energy, necessitating advanced energy storage solutions. Enhancing energy density is crucial for lowering system costs and enabling large‐scale deployment.
Xiaolian Zhao +8 more
wiley +1 more source
The Canadian Journal of Chemical Engineering, EarlyView.Polymeric and molecular amines embedded in hygroscopic matrices to facilitate CO2 transport for CO2/H2 separation. Abstract This work dealt with composite membranes comprising of polyvinylamine (PVAm) and triethylenetetramine (TETA) embedded in poly(vinyl alcohol) (PVA) for CO2/H2 separation via facilitated transport of CO2, where polymeric and ...
Steve Yijie Hu, Kean Wang, Xianshe Feng
wiley +1 more source
The research progress in polyethylene oxide polymer electrolytes
FlexMat, EarlyView.Polyethylene oxide (PEO) has become the mainstream matrix material for solid polymer electrolytes (SPEs) due to its excellent lithium salt complexation ability and processability. However, its high crystallinity results in low ionic conductivity at room temperature and difficulty in suppressing lithium dendrite growth, which significantly hinders the ...
Ying Wei +8 more
wiley +1 more source
Brain‐Inspired Neuromorphic Device for Artificial Intelligent Robots Applications
SmartBot, EarlyView.Brain‐inspired neuromorphic devices mimic biological systems to provide an efficient hardware foundation for embodied intelligent robotics. This review explores the material systems and corresponding computing architectures of neuromorphic devices that support low‐power perception, adaptive learning, and real‐time decision‐making.
Jiachen Han +3 more
wiley +1 more source