Results 11 to 20 of about 6,260 (167)

Nickel Phosphine Complexes: Synthesis, Characterization, and Behavior in the Polymerization of 1,3-Butadiene [PDF]

open access: yesMolecules
Several nickel dichloride phosphine complexes have been synthesized, their crystalline structure determined, and their behavior, in combination with methylaluminoxane, in the polymerization of butadiene has been examined.
Massimo Guelfi   +7 more
doaj   +2 more sources

From waste rubber to value polybutadiene modification for circular materials [PDF]

open access: yesNature Communications
Synthetic rubber waste poses a growing environmental challenge due to its cross-linked, non-recyclable nature. This Perspective examines emerging post-polymerization modification strategies for linear polybutadiene and vulcanized rubber, spanning ...
Janna Jeschke, Hatice Mutlu
doaj   +2 more sources

Preparation and characterization of polybutadiene rubber nased on hydrogen bond and dynamic borate ester bond

open access: yesHecheng xiangjiao gongye, 2021
Through the thiol-ene click reaction, the dihydroxyl functional group was grafted onto the polybutadiene(PB) molecular chain. And Tannic acid(TA) was successfully incorporated into dihydroxyl functionalized PB through the synergy of hydrogen bonding ...
REN Qing-chen, SHI Zi-xing
doaj   +1 more source

Preparation of high vinyl polybutadiene rubber via coordination polymerization with low-steric-hindrance alkoxy multi-substituted molybdenum

open access: yesHecheng xiangjiao gongye, 2022
A series of molybdenum based catalyst systems substituted with low alkoxy blocking ligands for the polymerization of 1,3-butadiene were synthesized, and polybutadiene with high vinyl content was prepared.
XIE Ting-hao; TANG Jian; GENG Jie-ting; WANG Xiao-tong; HUA Jing
doaj   +1 more source

Tribological Characterization of Some Elastomers Used at Progressive Cavity and Piston Pumps [PDF]

open access: yesMATEC Web of Conferences, 2020
The progressive cavity pump (PCP) is a positive displacement pump, consisting of a polished helical-shaped rod (rotor) turning inside a helical elastomer (stator).
Mohamed Iyad Al Naboulsi   +3 more
doaj   +1 more source

Repulsive bimodal atomic force microscopy on polymers

open access: yesBeilstein Journal of Nanotechnology, 2012
Bimodal atomic force microscopy can provide high-resolution images of polymers. In the bimodal operation mode, two eigenmodes of the cantilever are driven simultaneously.
Alexander M. Gigler   +5 more
doaj   +1 more source

Novel Cobalt Dichloride Complexes with Hindered Diphenylphosphine Ligands: Synthesis, Characterization, and Behavior in the Polymerization of Butadiene

open access: yesMolecules, 2019
Two novel cobalt diphenylphosphine complexes were synthesized by reacting cobalt(II) chloride with tert-butyl(diphenyl)phosphine (PtBuPh2) and (S)-(+)neomenthyldiphenylphosphine [(S)-NMDPP].
Giovanni Ricci   +4 more
doaj   +1 more source

Rheological Master Curves of Crystallizing Polymer Mixtures

open access: yesApplied Rheology, 2006
We present a simple methodology for extending linear viscoelastic measurements of crystallizing polymers to the high-frequency regime, where usually crystallization kinetics represents an obstacle. The idea is to perform rapid quenches, below the melting
Kapnistos M., Vlassopoulos D.
doaj   +1 more source

"Preparation of cardanol functionalized liquid 1,2-polybutadiene and enhancement of interfacial interaction on butadiene-styrene rubber/silica composites"

open access: yesHecheng xiangjiao gongye, 2022
Phenol functionalized liquid 1,2-PB (1,2-PB-g-CA) was prepared by grafting bio based cardanol (CA) onto 1,2-polybutadiene rubber (1,2-PB) by olefin metathesis.
GAO Wen-ke, ZHANG Wen-jing, LIU Jin-hui, HUA Jing?鄢
doaj   +1 more source

Chemical Upcycling of Nitrile Butadiene Rubbers to Polyamines and Polyols by Chemoselective Catalytic Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
We demonstrate here the transformation of NBR (Nitrile butadiene rubber) including post‐consumer waste sourced from nitrile gloves and o‐rings into polyamines and polyols via ruthenium catalyzed hydrogenation. ABSTRACT We report here two new approaches for the chemical recycling/upcycling of nitrile butadiene rubber (NBR) to make either polyamines or ...
Alejandra Sophia Lozano Perez   +7 more
wiley   +2 more sources

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