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Morphological Evidence for the Two-Step II–I Phase Transition of Isotactic Polybutene-1
Macromolecules, 2019Thin films of isotactic polybutene-1 (iPBu) with large lathlike flat-on form II crystals were prepared by isothermal crystallization from melt at 105 °C.
Rui Xin+6 more
semanticscholar +1 more source
Spherulite growth of polybutene-1 in a thermal gradient
Polymer Bulletin, 1990Polybutene-1 can form oriented spherulites when crystallized in a thermal gradient because the nucleation is suppressed in the high temperature region and the spherulite growth is obstructed except towards the high temperature. The difference of the growth rate in different radial directions leads to the change of the lamellar growth direction from ...
J. Petermann, Y. Huang
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Memory Effect on the Form II to I Phase Transition of Isotactic Polybutene-1 in a Flow Field
Macromolecules, 2023Wenjia Wei+5 more
semanticscholar +1 more source
Macromolecules, 2019
The mutual effects of long-chain branch and ionic functional groups on polybutene-1 (PB-1) phase transition from tetragonal form II into hexagonal form I of polybutene-1 were investigated using differential scanning calorimetry and various thermal ...
Chuanbin An+6 more
semanticscholar +1 more source
The mutual effects of long-chain branch and ionic functional groups on polybutene-1 (PB-1) phase transition from tetragonal form II into hexagonal form I of polybutene-1 were investigated using differential scanning calorimetry and various thermal ...
Chuanbin An+6 more
semanticscholar +1 more source
Melt Memory Effect beyond the Equilibrium Melting Point in Commercial Isotactic Polybutene-1
Industrial & Engineering Chemistry Research, 2019The memory effect denotes acceleration of crystallization kinetics in polymers when being cooled from the molten state. Using the method of differential scanning calorimetry (DSC), we found that a commercial isotactic polybutene-1 (i PB-1) sample showed ...
Peiru Liu, Yanhu Xue, Yongfeng Men
semanticscholar +1 more source
Equilibrium Melting Temperature of the Hexagonal Crystals of Polybutene-1 and Its Copolymer
Macromolecules, 2023Yanan Qin+3 more
semanticscholar +1 more source
, 2016
The new crystal structure models of forms I and II of isotactic polybutene-1 have been proposed by analyzing the 2-dimensional X-ray diffraction data measured for the highly oriented samples of almost pure crystal forms.
K. Tashiro+4 more
semanticscholar +1 more source
The new crystal structure models of forms I and II of isotactic polybutene-1 have been proposed by analyzing the 2-dimensional X-ray diffraction data measured for the highly oriented samples of almost pure crystal forms.
K. Tashiro+4 more
semanticscholar +1 more source