Results 11 to 20 of about 4,374 (220)
Nanoconfined Polyelectrolyte Multilayers
Lateral nanometer-scale control over the growth of polyelectrolyte (layer-by-layer) multilayers is demonstrated down to 40 nm, which is well below the natural size of the macromolecules in solution. Because of confinement upon adsorption, the molecules change conformation as compared with the usual, macroscopic case (see Figure). This work opens direct
A. Pallandre +3 more
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Formation of Polyelectrolyte Multilayers
A mechanism for the formation of polyelectrolyte multilayers is proposed. All of the experiments on such systems show that there is strong interpenetration of consecutive layers. We explain the very strong stability of the multilayers by the complexation between polyelectrolytes of opposite signs.
Castelnovo, Martin, Joanny, J.-F.
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Water and Ion Pairing in Polyelectrolyte Multilayers
The water content in multilayers made from poly(styrenesulfonate) and poly(diallyldimethylammonium chloride) was determined using infrared spectroscopy and thermal gravimetric analysis. Under ambient conditions the polyelectrolyte multilayer contains 10−20 wt % water, which is removed by heating under dry conditions to 100 °C.
Farhat, T +3 more
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Responsive polyelectrolyte multilayers
In this review we present selected recent developments of responsive multilayers formed by layer-by-layer assembly of oppositely charged polymers, with particular emphasis on the preparation of temperature- and pH-sensitive systems. We discuss the influence of the architecture and of the nature of the polyelectrolytes used on the responsive behavior of
Glinel, K. +5 more
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Polyelectrolyte Multilayers: An Overview on Fabrication, Properties, and Biomedical and Environmental Applications. [PDF]
Polyelectrolyte multilayers are versatile materials that are used in a large number of domains, including biomedical and environmental applications. The fabrication of polyelectrolyte multilayers using the layer-by-layer technique is one of the simplest ...
Petrila LM +3 more
europepmc +2 more sources
Lateral Mobility of Polyelectrolyte Chains in Multilayers
In this work, the lateral mobility of polyelectrolyte multilayers was investigated by means of the fluorescence recovery after photobleaching (FRAP) technique, with special attention to the effect of relevant parameters during and after preparation. Different polyelectrolytes with respect to charge density, stiffness, and hydrophilicity were compared ...
Nazaran, P. +4 more
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Encapsulation of Opiorphin in Polymer-coated Alginate Beads for Controlled Delivery and Painkilling [PDF]
Opiorphin (Oph) is a naturally produced endogenous peptide with a strong analgesic effect, superior to that of morphine, and without the severe side effects that morphine and morphine-like drugs exert.
Svetozar Stoichev +4 more
doaj +1 more source
Ion-Specific and Solvent Effects on PDADMA–PSS Complexation and Multilayer Formation
Among various parameters that influence the formation of polyelectrolyte complexes and multilayers, special emphasis should be placed on ion-specific and solvent effects.
Jasmina Jukić +4 more
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Wetting-Induced Polyelectrolyte Pore Bridging
Active layers of ion separation membranes often consist of charged layers that retain ions based on electrostatic repulsion. Conventional fabrication of these layers, such as polyelectrolyte deposition, can in some cases lead to excess coating to prevent
Anna Kalde +4 more
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Preventing S. aureus biofilm formation on titanium surfaces by the release of antimicrobial β-peptides from polyelectrolyte multilayers [PDF]
Benjamin D Gastfriend +2 more
exaly +2 more sources

