Results 181 to 190 of about 26,795 (292)

Porous cellulose nanofiber stringed HKUST-1 polyhedron membrane for air purification

open access: yesApplied Materials Today, 2019
Xing Zhao   +6 more
semanticscholar   +1 more source

A Cobotic, Digitally Controlled Schlenk‐line Unlocks Access to Elusive Lewis‐Base Stabilised Copper Bis(Disilylamides)

open access: yesAngewandte Chemie International Edition, EarlyView.
A Cobotic digital chemistry approach succeeds where manual synthesis failed. Herein, we present our new “AutoSchlenk” line which, coupled with other digital chemistry tools, was key to the synthesis and isolation of an unstable, and previously inaccessible, three‐coordinate Cu(II) hexamethylsilylamide complex. Abstract Silylamides are important ligands
Nicola L. Bell   +5 more
wiley   +1 more source

Cutting a Convex Polyhedron Out of a Sphere [PDF]

open access: green, 2010
Syed Ishtiaque Ahmed   +2 more
openalex   +1 more source

High‐Pressure Synthesis of Nitrogen‐Rich Y(N5)3·N2 Pentazolate with Perovskite Topology

open access: yesAngewandte Chemie International Edition, EarlyView.
Yttrium pentazolate, Y(N5)3·N2, with an exceptionally high nitrogen‐to‐metal ratio of 17:1 and perovskite topology, was synthesized from yttrium and nitrogen at 125 GPa and 3000 K in a laser‐heated diamond anvil cell. Abstract The discovery and stabilization of the cyclo‐N5⁻ anion have introduced a class of pentazolate compounds with significant ...
Andrey Aslandukov   +8 more
wiley   +1 more source

Tunable Endo/Exo Selectivity in Direct Catalytic Asymmetric 1,3‐Dipolar Cycloadditions with Polyfunctional Lewis Acid / Azolium‐Aryloxide Catalysts

open access: yesAngewandte Chemie International Edition, Accepted Article.
Catalytic asymmetric 1,3‐dipolar cycloadditions (1,3‐DCA) using iminoesters as ylide precursors offer a powerful approach to accessing stereochemically complex, biologically relevant pyrrolidines. While previous studies have already achieved impressive stereoselectivities, catalytic productivity remains a challenge, with turnover numbers (TON ...
Adrian Bürstner   +13 more
wiley   +1 more source

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