(NH4)2[Tc2O2(S2O7)4]: An Unexpected Technetium(V)‐Sulfate From the Reaction of (NH4)(TcO4) With SO3
The reaction of the radioactive pertechnetate (99TcO4)− with the oxidizer SO3 leads to blue crystals of (NH4)2[Tc2O2(S2O7)4]. The complex dimeric [Tc2O2(S2O7)4]2− anion exhibits the technetium in the oxidation state V, showing that reduction occurs during the reaction.
Stefan Sutorius +5 more
wiley +1 more source
Ultra-High Pressure Phosphor Based on an Eco-Friendly Perovskite Via Isovalent and Heterovalent Co-Doping Engineering. [PDF]
He X +9 more
europepmc +1 more source
ABSTRACT The chemical system Li/Ti/P has previously been subject to intensive investigation. However, reliable structural data for the reported phases have remained elusive. Motivated by the growing interest in phosphorus‐based lithium‐ion conductors, we have reinvestigated the synthesis, crystal structure, and physical properties of Li8TiP4.
David Müller +6 more
wiley +1 more source
Exploration of Ruthenium(II/III/VI)-Salen Complexes: From Synthesis to Functional Applications. [PDF]
Cristóvão B, Osypiuk D, Bartyzel A.
europepmc +1 more source
Uniform Gas Flow Distribution into Several Partial Flows under Consideration of Closable Outlets
The uniform distribution of a gas flow into several partial flows poses a challenge in various technical fields. This study presents a static flow distributor design that ensures an equal distribution of an inlet gas flow regardless of the flow rate and the number of open outlets.
Nikolas Schmidt +3 more
wiley +1 more source
High-Pressure Structural Evolution of Na<sub>2</sub>ZrSi<sub>2</sub>O<sub>7</sub> and Na<sub>2</sub>ZrSi<sub>2</sub>O<sub>7</sub>·H<sub>2</sub>O: Topology-Driven Compression Behaviors, Phase Stability, and Electronic Transitions. [PDF]
Zhang P +8 more
europepmc +1 more source
Graphical abstract illustrating the niobic acid precipitation process applied and the product obtained. Abstract This study investigates the precipitation of niobic acid (Nb2O5.nH2O) from potassium niobate solution with addition of sulphuric acid, and its subsequent thermal conversion into niobium oxide (Nb2O5). Thermodynamic modelling with PHREEQC and
Cássia R. Souza +4 more
wiley +1 more source
Monocular Near-Infrared Optical Tracking with Retroreflective Fiducial Markers for High-Accuracy Image-Guided Surgery. [PDF]
Moviglia JH, Stallkamp J.
europepmc +1 more source

