Results 161 to 170 of about 1,699 (208)
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Azine- and Imine-linked Conjugated PolyHIPEs through Schiff-Base Condensation Reaction

Polymer Chemistry, 2021
A new type of transition metal-free π-conjugated polyHIPEs is obtained by a Schiff-base condensation reaction coupled with a concentrated emulsion-based templating technique.
S. Kovačič   +4 more
semanticscholar   +1 more source

Exploring Hierarchically Porous Functional PolyHIPEs for Polymeric Support Designs: Synergistic Effects of VBC Content and Crosslinking on Surface Properties

Journal of Applied Polymer Science
In this study, high internal phase emulsions (HIPEs) with ranging vinyl benzyl chloride (VBC) contents (50–80 v/v%) were prepared to synthesize polyHIPEs with 90% nominal porosity having different ratios of Cl content.
Merve Süslükaya   +2 more
semanticscholar   +1 more source

A new route to carbon black filled polyHIPEs

Soft Matter, 2006
A series of carbon black filled polyHIPEs was synthesised following a new preparation protocol. 1 wt% carbon black was dispersed in the monomer mixture. In order to enhance the stability of the suspension, polymer grafting of carbon black was performed by initiating the polymerisation prior to emulsifying the formulation. All of the carbon black filled
Angelika, Menner   +2 more
openaire   +2 more sources

Preparation of hypercrosslinked PolyHIPEs by using a bio-derived monomer

European Polymer Journal, 2021
The interest on adapting bio-derived species to polymer synthesis has been increased in the last decade. Terpenes that can be obtained by extracting from the essential oils of tree sap and citrus fruit have an important place on this subject.
Burcu Kekevi, E. H. Mert
semanticscholar   +1 more source

Polymerization of MMA in polyHIPEs by RATRP

Journal of Polymer Research, 2014
A series of polymerized high internal phase emul- sions (polyHIPEs) with different cavities and windows (named PSD) were used as microreactors. Then methyl meth- acrylate (MMA) was polymerized in the spaces of the polyHIPE by reverse atom transfer radical polymerization (RATRP).
F. M. Sun   +3 more
openaire   +1 more source

PolyHIPEs from Divinyl Adipate: Preparation and Degradability

Macromolecular Chemistry and Physics, 2013
Using a high internal phase emulsion templating approach, highly porous open cellular polymers are prepared from divinyl adipate (DVA). The morphological structure of the monoliths includes cavities in the diameter range of around 5–25 μm and secondary interconnecting pores approximately 1 μm in diameter.
Marko Turnšek, Peter Krajnc
openaire   +1 more source

An environmentally benign post-polymerization functionalization strategy towards unprecedented poly(vinylamine) polyHIPEs

, 2021
Interconnected highly porous poly(vinylamine) monoliths are produced by post-polymerization hydrolysis of emulsion-templated poly(N-vinylformamide) polyHIPEs (polymerized high internal phase emulsions). Unlike previous work, in which polyHIPEs were amine-
Sarah Jurjevec   +3 more
semanticscholar   +1 more source

Ionic Liquids as Internal Phase for Non‐Aqueous PolyHIPEs

Macromolecular Rapid Communications, 2011
AbstractStable high internal phase emulsions (HIPEs) with the ionic liquid 1‐ethyl‐3‐methylimidazolium bis(trifluoromethyl‐sulfonyl)imide as dispersed phase were prepared and polymerised thermally into polyHIPEs. All polyHIPEs exhibited pore morphologies similar to that of polyHIPEs obtained with an aqueous dispersed phase.
Shirshova N.   +2 more
openaire   +2 more sources

Fabrication and evaluation of aminoethyl benzo-12-crown-4 functionalized polymer brushes adsorbents formed by surface-initiated ATRP based on macroporous polyHIPEs and postsynthetic modification

, 2020
For the efficient extraction of lithium ions (Li+) from salt-lake brines, adsorbents with high adsorption capacity, fast equilibrium rate, and excellent selectivity are urgently needed. Herein, aminoethyl benzo-12-crown-4 (2AB12C4) functionalized polymer
Pan Wang   +4 more
semanticscholar   +1 more source

PolyHipe:  A New Polymeric Support for Heterogeneous Catalytic Reactions:  Kinetics of Hydration of Cyclohexene in Two- and Three-Phase Systems over a Strongly Acidic Sulfonated PolyHipe

Industrial & Engineering Chemistry Research, 1999
A novel type of highly porous polymeric monolith called PolyHipe has been applied as a support for an immobilized catalyst (sulfonic acid). Somewhat differently from a conventional packed bed where the reaction mixture flows around the porous catalytic particles, here, the reaction mixture is forced through the pores of the monolith.
Ottens, M   +4 more
openaire   +1 more source

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