Synthesis and Functionalization of α-Olefines (6 and 10 Carbons)/Maleic Anhydride Comb-like Copolymers and Their Application in Silica Nanohybrid and Hydrogel [PDF]
Hypothesis: Poly(α-olefins) have non-polar structures and the development of polarity with different functionalities expands their application. The structure, number and size of the branches of the main chain affect the properties and design of new ...
Mohammad Reza Rostami Darounkola+4 more
doaj +1 more source
Kinetic and microstructural studies of Cp2ZrCl2 and Cp2HfCl2-catalyzed oligomerization of higher α-olefins in mPAO oil base stocks production [PDF]
Herein a quenched-flow kinetic technique was applied to calculate the rate constants of 1-hexene and 1-octene oligomerization catalyzed by the Cp2ZrCl2 and Cp2HfCl2/MAO catalyst systems, and subsequently a mechanism for the higher α-olefin ...
Ahad Hanifpour+4 more
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A Review of the Performance of Functionalized Waxes as a Compatibilizer and Co-Compatibilizer in Polymer Composites [PDF]
Demand for the use of polymers in different industries with different properties is increasing. However, pure polymer does not have the ability to create a wide range of desired features.
Mohammad Hadi Karimi+4 more
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Technologies and Catalysts for the Production of Polyethylene by Slurry Process: Patent Review [PDF]
For more than sixty years, thousands of patents and articles have been published annually on various manufacturing methods and comparing the properties and performance of manufactured polyethylenes.
hossein bazgir, zahra Zahra Issaabadi
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The Use of Electron Donors to Increase Stereospecificity in Ziegler-Natta Propylene Polymerization [PDF]
Different chemical components in traditional Ziegler–Natta catalytic system include: (1) titanium and vanadium containing compounds, mostly TiCl4, as an active centre, (2) trialkylaluminium-based Lewis acid compounds, especially triethylaluminium, as ...
Farshid Nouri-Ahangarani+2 more
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Synthesis of Branched Polymers and Dispersion of Nanosilica and the Effect of Their Interaction on Hydrated Cement Morphology [PDF]
Hypothesis: Dispersion and stabilization of silica nanoparticles are novel approach in the synthesis of hybrid materials in interacting with cement particles.
Mohammad Reza Rostami Darounkola+1 more
doaj +1 more source
Storage time effect on dynamic structure of MgCl2.nEtOH adducts in heterogeneous Ziegler-Natta catalysts [PDF]
Primary MgCl2.3.3EtOH adduct (PCT1) was prepared by melt quenching method and then submitted into a programmed thermal dealcoholation project using a fluidized bed reactor. During thermal dealcoholation program, different MgCl2.nEtOH support samples with
Najmeh Hadian+3 more
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MgCl2 Support Preparation Techniques and Their Effects on Ziegler-Natta Catalysts Performance in Propylene Polymerization [PDF]
A primary adduct of MgCl2.3.3EtOH (A0) was prepared by melt quenching and then it was further dealcoholated by thermal and chemical methods. In thermal dealcoholation, two different support samples with MgCl2.2.7EtOH (A1) and MgCl2.1.8EtOH (A2) formulas ...
Najmeh Hadian+3 more
doaj +1 more source
Ziegler-Natta Catalyst Preparation Process: Influential Parameters on Particles Morphology and Activity of Catalyst in Propylene Polymerization [PDF]
Different parameters including temperature and amount of titanium tetrachloride (TiCl4) were examined with respect to Ziegler-Natta catalyst morphology and the catalyst performance during its preparation process.
Hassan Arabi+3 more
doaj +1 more source
A practical criterion for synthesizing ethylen-1-butene copolymer in powder form in slurry polymerization with a Ziegler-Natta catalyst and predicting its incorporated 1-butene [PDF]
The concentration of ethylene and 1-butene in n-hexane as polymerization media was calculated at five different pressure levels (4, 6, 8, 10, and 12 bar) and four different 1-butene concentrations (0.13, 0.26, 0.39, and 0.52 mol/L) in n-hexane at T= 80°C
Mohsen Javaheri+2 more
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