Results 91 to 100 of about 28,742 (265)

Fabrication of macroporous POMs/biochar materials for fast degradation of phthalic acid esters through adsorption coupled with aerobic oxidation

open access: yesPolyoxometalates
Macroporous H5PMo10V2O40(n)/biochar (abbreviated as HPMoV(n)/biochar, where n is the loading amount of HPMo: 12 wt.%, 28 wt.%, 44 wt.%, 53 wt.%, and 63 wt.%) were fabricated from popcorn biocarbon and H5PMo10V2O40.
Qiwen Wang   +5 more
doaj   +1 more source

Research Progress of Polyoxometalate‐Integrated Frameworks: Syntheses, Properties, and Applications

open access: yesChemistryEurope, EarlyView.
This review systematically summarizes the integration of polyoxometalates with covalent organic frameworks, metal‐organic frameworks, hydrogen‐bonded organic frameworks, and emerging porous hosts. It highlights synergistic effects, synthesis strategies, and applications in catalysis, energy storage, sensing, and biomedicine, while addressing current ...
De‐Yin Wang   +6 more
wiley   +1 more source

Formation of Alkanes by Aerobic Carbon–Carbon Bond Coupling Reactions Catalyzed by a Phosphovanadomolybdic Acid [PDF]

open access: yes, 2017
The valorization of alkanes is possible via carbon–carbon coupling reactions. A series of dialkyl cobalt complexes [(RCH_2)_2Co^(III)(bpy)_2]ClO_4 (R = H, Me, Et, and Ph) were reacted with the H_5PV_2Mo_(10)O_(40) polyoxometalate as a catalyst, leading ...
Carmieli, Raanan   +6 more
core   +6 more sources

Keggin‐Type Aluminum Polyoxometalate‐Mediated Oxidation of Amorphous Carbon for Engineered Electrochemical Interfaces

open access: yesCarbon Energy, EarlyView.
Keggin‐type Al‐POM‐coated silica achieves selective surface oxidation of amorphous carbon through electrostatic attraction and proton‐coupled oxidation, tailoring interfacial properties for lithium‐ion batteries and semiconductor processes. ABSTRACT Amorphous carbon is widely used in energy storage and semiconductor technologies, where surface ...
Ganggyu Lee   +13 more
wiley   +1 more source

A Robust Framework Based on Polymeric Octamolybdate Anions and Copper(II) Complexes of Tetradentate N-donor Ligands [PDF]

open access: yes, 2018
A new organic-inorganic compound based on octamolybdate building blocks and copper(II) complexes of tetradentate N-donor ligands has been hydrothermally synthesized, namely [Cu(cyclam)](2)[Mo8O26]center dot 1.5H(2)O (1), (cyclam: 1,4,8,11 ...
Artetxe Arretxe, Beñat   +5 more
core   +4 more sources

Atomically Dispersed Pt1-Polyoxometalate Catalysts: How Does Metal-Support Interaction Affect Stability and Hydrogenation Activity?

open access: yesJournal of the American Chemical Society, 2019
Unlike nanostructured metal catalysts, supported single-atom catalysts (SACs) contain only atomically dispersed metal atoms, hinting at much more pronounced metal-support effects.
Bin Zhang   +6 more
semanticscholar   +1 more source

Recent Strategies Toward Durable and Ion‐Tolerant Transition Metal‐Based Electrocatalysts in Seawater Electrolysis

open access: yesCarbon Energy, EarlyView.
Recent strategies address these challenges through ion‐specific regulation, encompassing chloride‐tolerant and chloride‐regulating anodes together with cathode designs that suppress OH− accumulation and Mg2+/Ca2+ coupling. This ion‐management‐oriented framework provides general guidelines for achieving stable, selective, and scalable seawater ...
Lina Li   +5 more
wiley   +1 more source

Beyond Traditional Batteries—Emerging Systems for Next-Generation Energy Storage

open access: yesBatteries
Against the backdrop of the global energy transition, new energy battery technology plays an increasingly vital role in modern society, effectively addressing the intermittency of energy sources [...]
Xiaolin Tian, Yuqi Qin, Xiaoyuan Shi
doaj   +1 more source

Photocatalytic Activity of Monosized AuZnO Composite Nanoparticles

open access: yesApplied Sciences, 2018
Photocatalytic activity of monosized AuZnO composite nanoparticles with different compositions were synthesized by the one-pot polyol procedure, using the triblock copolymer poly(ethylene glycol)-block-poly(propylene glycol)-blockpoly(ethylene glycol ...
Chenguang Ma   +7 more
doaj   +1 more source

Novel Charge-Transfer Materials via Cocrystallization of Planar Aromatic Donors and Spherical Polyoxometalate Acceptors [PDF]

open access: yes, 2000
Spherical polyoxometalates (POMs) such as M6O192- and SiM12O404- (with M = Mo or W) and planar arene donors (anthracenes and pyrenes) can be cocrystallized (despite their structural incompatibility) by attaching a cationic “anchor” onto the arene which ...
Hubig, S. M.   +4 more
core   +1 more source

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