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Tuning the electrophilicity of vanadium-substituted polyoxometalate based ionic liquids for high-efficiency aerobic oxidative desulfurization

, 2020
With increasing stringent standard of sulfur content in fuels, deep desulfurization with high-efficiency is necessary for ecological and environmental demands. Herein, vanadium-substituted polyoxometalate-based ionic liquids with tunable electrophilicity
Ming Zhang   +9 more
semanticscholar   +1 more source

Immobilization of polyoxometalate-based sulfonated ionic liquids on UiO-66-2COOH metal-organic frameworks for biodiesel production via one-pot transesterification-esterification of acidic vegetable oils

Chemical Engineering Journal, 2019
In accordance with the need of green and cleaner production, the aim of the present study is to fabricate an organic-inorganic hybrid recyclable catalyst with both Bronsted and Lewis acid sites for the one-pot production of biodiesel from the low-cost ...
Wenlei Xie, Fei Wan
semanticscholar   +1 more source

Boosting the Pseudocapacitive and High Mass‐Loaded Lithium/Sodium Storage through Bonding Polyoxometalate Nanoparticles on MXene Nanosheets

Advanced Functional Materials, 2021
Achieving rate‐capable and high mass‐loaded lithium/sodium storage plays a pivotal role in promoting real world applications of many emerging electrode materials.
Huixia Chao   +11 more
semanticscholar   +1 more source

Mo2C-Derived Polyoxometalate for NIR-II Photoacoustic Imaging-Guided Chemodynamic/Photothermal Synergistic Therapy.

Angewandte Chemie, 2019
To overcome the current limitations of Chemodynamic therapy (CDT), we herein propose readily synthesized Mo 2 C-derived polyoxometalate (POM) as a new CDT agent which permits synergistic chemodynamic and photothermal therapy operating in the second near ...
Gongyuan Liu   +8 more
semanticscholar   +1 more source

Polyoxometalate-Based Molecular Materials

Chemical Reviews, 1998
Molecule-based materials with active physical properties, in particular electrical, magnetic, and optical, are a focus of contemporary materials chemistry research. Certainly, one reason for this interest has been the realization that these materials can exhibit cooperative properties typically associated with the inorganic network solids, as for ...
Eugenio, Coronado   +1 more
openaire   +2 more sources

Photocatalytic remediation of organic waste over Keggin-based polyoxometalate materials: A review.

Chemosphere, 2021
Photocatalytic remediation of industrial water pollution has courted intense attention lately due to its touted green approach. In this respect, Keggin-based polyoxometalates (POMs) as green solid acids in photocatalytic reaction possess superior ...
S. Y. Lai   +5 more
semanticscholar   +1 more source

The Intrinsic Charge Carrier Behaviors and Applications of Polyoxometalate Clusters Based Materials

Advances in Materials, 2021
Polyoxometalates (POMs) are a series of molecular metal oxide clusters, which span the two domains of solutes and solid metal oxides. The unique characters of POMs in structure, geometry, and adjustable redox properties have attracted widespread ...
Le Yang   +6 more
semanticscholar   +1 more source

Ionothermal Synthesis of Polyoxometalates

Angewandte Chemie International Edition, 2011
An emerging approach: In the ionothermal synthesis of transition-metal-oxide clusters an ionic liquid acts as a solvent, structure-directing agent, and charge-compensating species. The method may open new convenient routes for the synthesis of polyoxometalate-based materials.
Ahmed, E., Ruck, M.
openaire   +3 more sources

Rare Earth Polyoxometalates

Accounts of Chemical Research, 2017
Longstanding and important applications make use of the chemical and physical properties of both rare earth metals and polyoxometalates of early transition metals. The catalytic, optical, and magnetic features of rare earth metal ions are well-known, as are the reversible multielectron redox and photoredox capabilities of polyoxomolybdates and ...
openaire   +3 more sources

Imidoylation of polyoxometalates and fabrication of chiral polyoxometalates

Chinese Science Bulletin, 2011
The synthesis of chiral polyoxometalates (POMs) has attracted increasing attention in recent years. The aim of this research was to construct different rigid POMs with organic derivatives. The POMs were synthesized with C–C or C–N links using N,N' -dicyclohexylcarbodiimide (DCC) protocol.
Jin ZHANG   +5 more
openaire   +1 more source

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