Results 21 to 30 of about 28,742 (265)

Selective targeting of proteins by hybrid polyoxometalates: Interaction between a bis-biotinylated hybrid conjugate and avidin [PDF]

open access: yes, 2018
The Keggin-type polyoxometalate [\u3b3-SiW10O36]8 12 was covalently modified to obtain a bis-biotinylated conjugate able to bind avidin. Spectroscopic studies such as UV-vis, fluorimetry, circular dichroism, coupled to surface plasmon resonance technique
Alessandra Saccani   +12 more
core   +2 more sources

Synthetic considerations in the self-assembly of coordination polymers of pyridine-functionalised hybrid Mn-Anderson polyoxometalates [PDF]

open access: yes, 2017
The incorporation of polyoxometalates (POMs) as structural units into ordered porous constructs such as metal-organic frameworks (MOFs) is desirable for a range of applications where intrinsic properties inherited from both the MOF and POM are utilised ...
Forgan, Ross S.   +3 more
core   +1 more source

DESTRUCTION OF POLYOXOMETALATE {Mo72Fe30} AS A TRANSPORT AGENT IN BLOOD SIMULATING MEDIA, ITS STABILIZATION BY ALBUMIN

open access: yesФизико-химические аспекты изучения кластеров, наноструктур и наноматериалов, 2020
The creation and use of the targeted drug delivery systems based on nanocluster polyoxometalate {Mo72Fe30} implies its destruction in the body, accompanied by the gradual release of the drug.
M.O. Tonkushina   +4 more
doaj   +1 more source

Current rectification in a single molecule diode: the role of electrode coupling [PDF]

open access: yes, 2015
We demonstrate large rectification ratios (> 100) in single-molecule junctions based on a metal-oxide cluster (polyoxometalate), using a scanning tunneling microscope (STM) both at ambient conditions and at low temperature. These rectification ratios are
Agrait, Nicolas   +5 more
core   +1 more source

Shrink wrapping redox-active crystals of polyoxometalate open frameworks with organic polymers via crystal induced polymerisation [PDF]

open access: yes, 2016
We report examples of crystal surface modification of polyoxometalate open frameworks whereby the use of pyrrole or aniline as monomers leads to the formation of the corresponding polymers via an oxidative polymerization process initiated by the redox ...
Cronin, Lee   +3 more
core   +1 more source

Polyoxometalate (POM)-layered double hydroxides (LDH) composite materials: design and catalytic applications [PDF]

open access: yes, 2017
Layered double hydroxides (LDHs) are an important large class of two-dimensional (2D) anionic lamellar materials that possess flexible modular structure, facile exchangeability of inter-lamellar guest anions and uniform distribution of metal cations in ...
Li, Tengfei   +2 more
core   +1 more source

Extending Metal-to-Polyoxometalate Charge Transfer Lifetimes: The Effect of Heterometal Location [PDF]

open access: yes, 2014
In an effort to develop robust molecular sensitizers for solar fuel production, the electronic structure and photodynamics of transition-metal-substituted polyoxometalates (POMs), a novel class of compound in this context, was examined.
Acerete   +77 more
core   +1 more source

Preparation and Characterization of Biodegradable κ-Carrageenan Based Anti-Bacterial Film Functionalized with Wells-Dawson Polyoxometalate

open access: yesFoods, 2022
In the present study, an anti-bacterial film (Carr/POM film) was prepared through the incorporation of Wells-Dawson polyoxometalate K6[Mo18O62P2] into κ-carrageenan-based polymers using the tape-casting method.
Fenghua Zhou   +6 more
semanticscholar   +1 more source

A double-tartrate-bridged deca-nuclearity europium-tungsten cluster embedded selenotungstate and its selective optical sensing of o-nitrophenol

open access: yesPolyoxometalates, 2023
An inorganic–organic hybrid Eu–W-implanted tartrate-connected selenotungstate tetramer {[Eu4(H2O)12W6O12(tar)2][B-α-SeW9O33]4}16− (1a, H4tar = tartaric acid) was successfully obtained by introducing the flexible multidentate tartrate ligand into the Se ...
Yong-Chao Dai   +6 more
doaj   +1 more source

Polyoxometalate‐Single Atom Catalysts (POM‐SACs) in Energy Research and Catalysis

open access: yesAdvanced Energy Materials, 2021
Single atom catalysts—SACs—have received intense interest in sustainable energy research due to their enormous application potential and broad catalytic scope.
Rongji Liu, C. Streb
semanticscholar   +1 more source

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