Results 1 to 10 of about 11,067 (216)

Recent advances in polyoxometalate-based lanthanide–oxo clusters

open access: yesPolyoxometalates, 2023
Polyoxometalate (POM)-based lanthanide-oxo clusters (LnOCs) are a class of polynuclear lanthanide–oxygen complexes formed by polyoxometalate stabilization through oxygen bridges in which POMs can be viewed as multidentate inorganic ligands.
Shu-Rong Li   +4 more
doaj   +1 more source

Photoactive hourglass-type M{P4Mo6}2 networks for efficient removal of hexavalent chromium

open access: yesPolyoxometalates, 2023
The exploration of high-efficiency photocatalysts to drive the conversion of highly toxic heavy metal hexavalent chromium (Cr(VI)) in wastewater to low-toxic trivalent chromium (Cr(III)) is of great significance for purifying water that contains emerging
Xiao-Yu Yin   +6 more
doaj   +1 more source

Synthesis, Characterization and Dye Removal Behavior of Core–Shell–Shell Fe3O4/Ag/Polyoxometalates Ternary Nanocomposites

open access: yesNanomaterials, 2019
The ternary nanocomposites Fe3O4/Ag/polyoxometalates (Fe3O4/Ag/POMs) with core−shell−core nanostructure were synthesized by coating [Cu(C6H6N2O)2(H2O)]H2[Cu(C6H6N2O)2(P2Mo5O23)]·4H2O polyoxometalates on the surface of Fe3O4/Ag (core ...
Shixia Zhan   +6 more
doaj   +1 more source

Structural modification and performance regulation of atomically precise metal nanoclusters by phosphine

open access: yesPolyoxometalates, 2023
The ligand exchange-induced size/structural transformation (LEIST) reaction of metal nanoclusters gives researchers an effective way to understand the structural transition, broaden the methods of synthesis, and enhance the relevant performance of metal ...
Wenwen Fei   +4 more
doaj   +1 more source

Synthetic considerations in the self-assembly of coordination polymers of pyridine-functionalised hybrid Mn-Anderson polyoxometalates [PDF]

open access: yes, 2017
The incorporation of polyoxometalates (POMs) as structural units into ordered porous constructs such as metal-organic frameworks (MOFs) is desirable for a range of applications where intrinsic properties inherited from both the MOF and POM are utilised ...
Forgan, Ross S.   +3 more
core   +1 more source

Preparation of Fe3O4@polyoxometalates Nanocomposites and Their Efficient Adsorption of Cationic Dyes from Aqueous Solution

open access: yesNanomaterials, 2019
In this work, two magnetic adsorbents Fe3O4@1 and Fe3O4@2 were prepared by combining Fe3O4 nanoparticles and polyoxometalate hybrids [Ni(HL)2]2H2[P2Mo5O23]·4H2O (1), [H2L]5H[P2Mo5O23]·12H2O (2) (HL = 2-acetylpyridine-thiosemicarbazone).
Jie Li   +5 more
doaj   +1 more source

Tetrameric cubane Al9Ln7 (Ln = Ce, Pr, Nd) clusters as aldol addition catalysts

open access: yesPolyoxometalates, 2023
Studies on the preparation, structures, and properties of heterometallic complexes are currently of great interest because of their emergent synergistic properties.
Xiao-Yu Liu   +4 more
doaj   +1 more source

Selective targeting of proteins by hybrid polyoxometalates: Interaction between a bis-biotinylated hybrid conjugate and avidin [PDF]

open access: yes, 2018
The Keggin-type polyoxometalate [\u3b3-SiW10O36]8 12 was covalently modified to obtain a bis-biotinylated conjugate able to bind avidin. Spectroscopic studies such as UV-vis, fluorimetry, circular dichroism, coupled to surface plasmon resonance technique
Alessandra Saccani   +12 more
core   +2 more sources

A Magnetic Adsorbent for the Removal of Cationic Dyes from Wastewater

open access: yesNanomaterials, 2018
In this article, a study was presented on the adsorption activity of a new nanocomposite particle Fe3O4@1, which was synthesized by combining [Cu(HL)2]2H2[P2Mo5O23]·10H2O (1) (HL = 2-acetylpyridine semicarbazone) and Fe3O4 nanoparticles ...
Yumei Ji   +6 more
doaj   +1 more source

Metal ion-induced alloying and size transformation of water-soluble metal nanoclusters

open access: yesPolyoxometalates, 2023
The development of novel strategies for the synthesis of water-soluble alloy nanoclusters (NCs) and investigations of their alloying mechanisms are highly desirable.
Shuyu Qian   +6 more
doaj   +1 more source

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