Results 41 to 50 of about 1,361 (213)

Thiuram Vulcanization Accelerators as Polysulfide Scavengers To Suppress Shuttle Effects for High-Performance Lithium–Sulfur Batteries [PDF]

open access: yes, 2019
Lithium–sulfur (Li–S) batteries are considered to be one of the most promising alternatives for next-generation high energy-density storage systems.
Chenyang Shi   +13 more
core   +1 more source

Beyond the Polysulfide Shuttle and Lithium Dendrite Formation: Addressing the Sluggish Sulfur Redox Kinetics for Practical High‐Energy Li‐S Batteries [PDF]

open access: yes, 2020
Electrolyte modulation simultaneously suppresses polysulfide the shuttle effect and lithium dendrite formation of lithium–sulfur (Li-S) batteries. However, the sluggish S redox kinetics, especially under high S loading and lean electrolyte operation, has
Zhao, Chen   +7 more
core   +1 more source

Oligoanilines as a suppressor of polysulfide shuttling in lithium–sulfur batteries

open access: yesMaterials Horizons, 2017
Amine-capped aniline trimer (ACAT) with a strong interaction with polysulfides (LiPS) facilitates the formation of bulky ACAT–LiPS complexes, which are then size-selectively sieved and stabilized within the cathode in lithium–sulfur batteries.
Chi-Hao Chang   +3 more
openaire   +2 more sources

High Entropy Sulfide Nanoparticles as Lithium Polysulfide Redox Catalysts [PDF]

open access: yes, 2023
The polysulfide shuttle contributes to capacity loss in lithium–sulfur batteries, which limits their practical utilization. Materials that catalyze the complex redox reactions responsible for the polysulfide shuttle are emerging, but foundational ...
Connor R. McCormick (9073678)   +4 more
core   +1 more source

High-wettability and Fire Resistant Separator Efficient Polysulfide Barrier for Increased Electrochemical Activity

open access: yesInternational Journal of Electrochemical Science, 2019
The common polypropylene separator could provide pathways for the transportation for the lithium- ions. However, it fails to inhibit the polysulfide migration during the electrochemical reactions.
Jiaofei Huo, Yinwei Wang
doaj   +1 more source

A New Graphitic Nitride and Reduced Graphene Oxide-Based Sulfur Cathode for High-Capacity Lithium-Sulfur Cells

open access: yesEnergies, 2022
Lithium-sulfur (Li-S) batteries can provide at least three times higher energy density than lithium-ion (Li-Ion) batteries. However, Li-S batteries suffer from a phenomenon called the polysulfide shuttle (PSS) that prevents the commercialization of these
Artur M. Suzanowicz   +5 more
doaj   +1 more source

Reduced Polysulfide Shuttle Effect by Using Polyimide Separators with Ionic Liquid-based Electrolytes in Lithium-Sulfur Battery [PDF]

open access: yes, 2017
In this research, we demonstrate a new method for reducing the shuttle effect by confining polysulfide in separator area through the use of polyimide (PI) separator with reversible adsorption functions in lithium-sulfur batteries.
Wang, Yanqing   +15 more
core   +1 more source

Surface/Interface Structure and Chemistry of Lithium–Sulfur Batteries: From Density Functional Theory Calculations’ Perspective

open access: yesAdvanced Energy & Sustainability Research, 2021
Nowadays, the rapid development of portable electronic products and low‐emission electric vehicles is putting forward higher requirements for energy‐storage systems.
Jiadong Shen   +8 more
doaj   +1 more source

Hierarchical Primary‐Secondary Coordination Synchronizes Ion Flux and Sulfur Redox in Solid Polymer Electrolytes

open access: yesAdvanced Functional Materials, EarlyView.
Hierarchical coordination engineering redistributes Li+ from anion‐dominated pairing toward polymer‐mediated binding. Strong primary sites promote salt dissociation, while distributed secondary sites sustain dynamic hopping pathways. This coordination landscape couples ion flux with polysulfide conversion, suppresses transport‐conversion decoupling ...
Zhong‐Wei Zheng   +8 more
wiley   +1 more source

Multifunctional Cellulose Nanocrystals as a High-Efficient Polysulfide Stopper for Practical Li–S Batteries [PDF]

open access: yes, 2020
Because of the severe shuttle effect of polysulfides, achieving durable Li-S batteries is still a great challenge, especially under practical operation conditions including the high sulfur content, high loading, and high operation temperature.
Liu, Jie   +11 more
core   +1 more source

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