Results 71 to 80 of about 11,831 (256)

Fe Atoms Accelerator Coupled With Oxygen Vacancies Channel Synergistically Boost OER Performance of Fe‐CoMoO4‐Ov Nanosheets

open access: yesCarbon Energy, EarlyView.
Fe‐CoMoO4‐Ov/NF demonstrates significantly improved OER catalytic performance compared to CoMoO4. Specifically, the introduced Fe atoms act as a promoter for surface reconstruction, significantly reducing the energy required for surface reconstruction to generate FeCoOOH. The oxygen vacancies serve as electron channels between the core Fe‐CoMoO4‐Ov and
Chaojie Lyu   +4 more
wiley   +1 more source

Slab Tearing and Recycled Continental Sediments in the Lithospheric Mantle: Geodynamic Insights From Miocene Alkaline Rocks of the Tangra‐YumCo Rift, Southern Tibet

open access: yesGeochemistry, Geophysics, Geosystems
Mantle metasomatism is a common phenomenon in convergent margins; however, metasomatism by subducted sediments and their role in alkaline magma generation remain poorly understood.
Esteban Jarquín, Rui Wang
doaj   +1 more source

Research Progress on V2CTx MXene‐Based Composites: Synthetic Strategies, Structure Design, and Multifunctional Applications

open access: yesCarbon Energy, EarlyView.
This review systematically and comprehensively summarizes the latest research progress on V2CTx MXene. Focusing on the structural design strategies, particularly the construction of the V2CTx‐based hetero‐composite structure. Furthermore, widespread applications including electrochemical energy storage and conversion, as well as photocatalytic ...
Wenjun Zhu   +9 more
wiley   +1 more source

Challenges of Bio‐Syngas Conversion to High‐Value‐Added Liquid Chemicals and Fuels via COx Hydrogenation

open access: yesCarbon Energy, EarlyView.
Converting biomass‐derived syngas into value‐added fuels and chemicals offers a promising route toward carbon neutrality, yet unfavorable H2/COx ratios, elevated CO2 levels, and trace impurities pose persistent obstacles. This review examines strategies spanning syngas conditioning, impurity‐tolerant catalyst development, and integrated process design,
Xuan Bie   +7 more
wiley   +1 more source

Silica‐Supported Mononuclear Methyl‐Platinum Complexes Stabilized by Trimethylphosphine—Synthesis, Structure, and Reactions Under Reducing Conditions

open access: yesChemistry – A European Journal, EarlyView.
The article describes the synthesis and molecular transformations of a silica‐supported bis(phosphine)methylplatinum(II) complex under reactive (H2, CO) and inert gas atmospheres. The focus lies on the stabilizing effect of the sterically non‐demanding trimethylphosphine ligand, which alters the reactivity of the surface sites, compared to other ...
Lea S. Kopietz   +6 more
wiley   +1 more source

Bismuth Chalcogenide‐Based Photocatalysts for Nitrogen Reduction: Recent Progress and Prospects

open access: yesChemistry – A European Journal, EarlyView.
Bismuth chalcogenides emerge as promising visible‐light photocatalysts for sustainable ammonia synthesis, driven by tunable electronic structures and strong N2 activation. Recent advances reveal how defects, doping and heterojunction design synergistically enhance charge separation and reactivity. Key challenges and future directions highlight pathways
Mukesh K. Verma   +4 more
wiley   +1 more source

Assessment of the Contamination Level of a Podzolized Chernozem with Nuclides in a Long-term Land Use

open access: yesAgriculture, 2019
Prolonged systematic application of mineral fertilisers contributes to increasing the yielding capacity of agricultural crops. However, it can lead to significant changes in the composition, properties and formation of agricultural soil regimes.
Hospodarenko Hrygorii   +3 more
doaj   +1 more source

Bis(2‐Adamantyl)Magnesium: Synthesis, Structure, and Applications of a Versatile and Shelf‐Stable 2‐Adamantyl Anion Equivalent

open access: yesChemistry – A European Journal, EarlyView.
At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta   +3 more
wiley   +1 more source

Cellular Membrane‐Targeted Europium(III) Probe for Selective and Time‐Resolved Detection of Peroxynitrite

open access: yesChemistry – A European Journal, EarlyView.
We report a cellular membrane‐targeted europium(III) probe, Eu.Chol, that enables selective, time‐resolved detection of peroxynitrite (ONOO−) at the cell membrane interface. Eu.Chol demonstrates efficient incorporation into liposomes and Jurkat cells, with minimal response to H2O2, establishing a modular platform for subcellular ONOO− sensing ...
Jamie Webb   +6 more
wiley   +1 more source

Non‐Covalent Fluorine–Silica Anchoring of a Molecular Platinum(II) bis(NHC) Catalyst: Structure, Interface Control, and Hydrosilylation Activity

open access: yesChemistry – A European Journal, EarlyView.
A Pt(II) bis(NHC) complex is immobilized on mesoporous silica through directional F–Si interactions encoded in the ligand framework. Quantitative 19F{29Si} REDOR experiments and molecular dynamics simulations establish Å‐scale catalyst–support contacts and define the interfacial organization.
Alexander Bergen   +10 more
wiley   +1 more source

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