The reaction between the methanol radical cation and sulfur dioxide is remarkably fast and forms several ionic and neutral products (HOSOH+, CH2OSO+, CH2OH+, CH2O, H2O, HSO2). The chemistry goes beyond simple proton or hydrogen transfer, revealing a close interaction between the two species, relevant to atmospheric and astrochemical environments where ...
Mauro Satta +3 more
wiley +1 more source
Optical diagnostics of low-pressure RF-DBD Ar/CH₄ plasma: mapping electron temperature and density versus power, pressure, and gas flow. [PDF]
Yelubayev DY +8 more
europepmc +1 more source
Ni2 bispincer complexes with an embedded central imido anchor are presented. The bispincer complexes leverage the high basicity of imido ligands to facilitate 1,2 addition of weak B─H and Si─H bonds, resulting in hydrido–amido complexes and resultingly a contortion of a Ni─Ni sigma bond to form an S = 1 species. The 1,2 addition is proposed to serve as
David de los Santos +2 more
wiley +1 more source
Technoeconomic and Environmental Assessments of CO<sub>2</sub> Methanation and Liquefaction for Climate Mitigation. [PDF]
Choe C +6 more
europepmc +1 more source
Ru nanoparticles confined within mesoporous SiOx‐pillared montmorillonite exhibit exceptional performance for CO2 methanation. The catalyst maintains a high reaction rate even at elevated CO2 conversion while preserving high Ru mass–specific activity, overcoming typical inhibition by H2O and CO observed in conventional supported Ru catalysts.
Seunghwan Jung +4 more
wiley +1 more source
Research on carbon emission models and emission characteristics in the coal development process. [PDF]
Gang W +7 more
europepmc +1 more source
Tris(indol‐3‐yl)methanes were synthesized from indoles, CO2, and PhMe2SiH in the presence of BPh3 in acetonitrile at 50°C. One product, tris(4‐bromo‐1‐methylindol‐3‐yl)methane, underwent a palladium‐catalyzed cascade reaction for the formation of a novel polycyclic heteroaromatic compound, where the methine C(sp3) atom originating from CO2 was ...
Sha Li +5 more
wiley +1 more source
Enhanced Explosion Characteristics of Methane/Air Induced by Barium Nitrate under a Large Horizontal Pipeline. [PDF]
Sun W, Chen Y, Li D.
europepmc +1 more source
Design of Solar Energy Harvesting Reactor From 2D to 3D Structures for Solar Thermal Conversion
ABSTRACT Solar energy utilisation is pivotal for advancing sustainable and renewable energy solutions, yet the rational design of high‐efficiency photothermal conversion devices remains a critical challenge. This paper systematically examines the evolution of photothermal reactor architectures from two‐dimensional (2D) to 3D structures, emphasising ...
Haozhe Zhuang +8 more
wiley +1 more source
Recent Advances in Pd-Decorated SnO<sub>2</sub> Nanowires Toward Room-Temperature Methane Sensing: A Mini-Review of Synthesis Strategies, Catalytic Mechanisms, and Mining Safety Applications. [PDF]
Radebe MM, Cingo X, Thembela HK.
europepmc +1 more source

