Results 171 to 180 of about 14,028 (253)

Polarity‐Directed Synthesis of an Exfoliable 2D Polyoxometalate‐Based Metal‐Organic Framework for Noble Metal‐Free Alkyne Transfer Semi‐Hydrogenation

open access: yesAngewandte Chemie, EarlyView.
Exfoliation of 2D nanosheets based on polyoxometalate metal‐organic frameworks (POMOFs) gives access to nanostructures with selective catalytic reactivity for the alkyne transfer semi‐hydrogenation which outperform the bulk references and rival some classical noble metal‐based catalysts.
Xusheng Dai   +10 more
wiley   +2 more sources

Coordination‐Driven Direct C─H Metalation of N‐Heterocycles With a Superbasic Co(II) Amide Co(TMP)2

open access: yesAngewandte Chemie, EarlyView.
By enabling regioselectivities that are inaccessible with conventional bases, this study introduces a Co(II) amide platform for the deprotonative C─H metalation of sensitive N‐heterocycles. Subsequent interception of the resulting Co(II) intermediates with external oxidants affords a family of sterically congested, TMP‐substituted heterocycles via C─N ...
Na Jin   +3 more
wiley   +1 more source

Matching the Coupling of Valence Electrons in the Oxide Interface to Perturb the Magnetic Order Enhancing Oxygen Reduction in Zinc–Air Batteries

open access: yesAngewandte Chemie, EarlyView.
Sub‐5 nm Fe2O3/Sm2O3 heterojunction nanoparticles are anchored on nitrogen‐doped carbon nanofibers, featuring coupled Fe(3d)‐O(2p)‐Sm(4f) orbitals at the interface. The resulting super‐exchange induces antiparallel magnetic ordering at heterointerfaces, suppressing spin‐dependent interaction between surface OH* species and Fe sites to facilitate OH ...
Jing Li   +9 more
wiley   +1 more source

Strain Engineering via W–O–Ru Interfacial Coupling to Suppress Lattice Oxygen Activation for Stable Acidic Water Electrolysis

open access: yesAngewandte Chemie, EarlyView.
Constructing atomically coupled W–O–Ru interfacial units on RuO2 triggers a dynamic strain evolution during the oxygen evolution reaction. An initial tensile strain secures structural stability, while a self‐adjusting transition to interfacial compression optimizes catalytic activity.
Yi Guan   +7 more
wiley   +1 more source

Unbiased Structure Prediction of Sophisticated Cage Structures

open access: yesAngewandte Chemie, EarlyView.
We introduce the software and workflow for automated, unbiased exploration of all possible connectivities of a given set of building blocks and their stoichiometry to predict stable cage structures. ABSTRACT Cage structure prediction has made significant strides by generating structures based on what the community has seen before.
Andrew Tarzia, Giovanni M. Pavan
wiley   +1 more source

Sustainable Pd‐Catalyzed Aminations “on Dirty Water”

open access: yesAngewandte Chemie, EarlyView.
Aminations, done safely yet neat, and therefore, quickly, using low levels of Pd, in “dirty water” that must contain 30% KOH; not NaOH, and not at 5%,10%, 20%, 40%, or 50% KOH. Moreover, no base sensitivity of functional groups! Very cool. Thank you, Nature.
Erfan Oftadeh   +4 more
wiley   +1 more source

Pulsed‐Laser Ablation for the Synthesis of High‐Entropy Alloy Aerogels Toward H2O2 Production and Water Decolorization

open access: yesAngewandte Chemie International Edition, EarlyView.
This work establishes a universal strategy for fabricating compositionally complex solid solution alloy aerogels via pulsed‐laser ablation and the sol‐gel process. The electrocatalytic capabilities of these aerogels are subsequently evaluated for H2O2 electrosynthesis and water treatment applications.
Cui Wang   +10 more
wiley   +1 more source

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